Preface ........................................................ xi
Letter from Dr. Hermann Grunder - ANL ........................ xiii
Photographs & Comments ........................................ xiv
Organization ................................................. xvii
List of Participants ........................................ xviii
Chapter 1:
New Carbon Materials for Supercapacitors ...................... 1
Subject Overview ............................................ 3
Novel Carbonaceous Materials for Application in
the Electrochemical Supercapacitors ......................... 5
E. Frackowiak, J. Machnikowski and F. Béguin
Effect of Carbonaceous Materials on Performance of
Carbon-Carbon and Carbon-Ni Oxide Types of
Electrochemical Capacitors with Alkaline Electrolyte ....... 21
A.I. Belyakov
Hybrid Supercapacitors Based on a-MnO2/Carbon
Nanotubes Composites ....................................... 33
V. Khomenko, E. Raymundo-Piñero and F. Béguin
Development of Supercapacitors Based on Conducting
Polymers ................................................... 41
V. Khomenko, E. Frackowiak, V. Barsukov, and F. Béguin
Supercapacitors: Old Problems and New Trends ............... 51
Y. Malein, N. Strizhakova, V. Izotov, A. Mironova,
S. Kozachkov, V. Danilin and S. Podmogilny
Modeling Porosity Development During KOH Activation of
Coal and Pitch-Derived Carbons for Electrochemical
Capacitors ................................................. 63
K. Kierzek, G. Gryglewicz and J. Machnikowski
General Properties oflonic Liquids as Electrolytes for
Carbon-Based Double Layer Capacitors ....................... 73
A. Lewandowski and M. Galinski
Chapter 2:
Carbon Materials for Gas Diffusion Electrodes, Metal Air
Cells and Batteries .......................................... 85
Subject Overview ........................................... 87
New Concept for the Metal-Air Batteries Using Composites:
Conducting Polymers/Expanded Graphite as Catalysts ......... 89
V.Z. Barsukov, V.G. Khomenko, A.S. Katashinskii and
T.I. Motronyuk
Mechanically Rechargeable Magnesium-Air Cells with
NaCl-Electrolyte .......................................... 105
A. Kaisheva and I. Iliev
Application of Carbon-Based Materials in Metal-Air
Batteries: Research, Development, Commercialization ....... 117
A. Kaisheva and I. Iliev
Metal - Air Batteries with Carbonaceous Air Electrodes
and Nonmetallic Catalysts ................................. 137
N. Korovin
Chapter 3:
Carbon Anodes for Lithium-Ion Batteries ..................... 151
Subject Overview .......................................... 153
Carbonaceous Materials for Batteries ...................... 157
T. Takamura and R.J. Brodd
Anode-Electrolyte Reactions in Li Batteries:
The Differences Between Graphitic and Metallic Anodes ..... 171
W.J. Santner, K.C. Möller, W. Kohs, C. Veil, E. Lanzer,
A. Trifonova, M.R. Wagner, P. Raimann, C. Korepp,
J.O. Besenhard and M. Winter
Performance of Novel Types of Carbonaceous Materials in
the Anodes of CLAiO's Lithium-Ion Battery Systems ......... 189
M. Walkowiak, K. Knofczynski, D. Waszak, M. Kopczyk,
M. Rusinek and J. Machnikowski
Why Graphite Electrodes Fail in PC Solutions: An Insight
from Morphological Studies ................................ 197
D. Aurbach, M. Koltypin, H. Teller and Y.S. Cohen
New Developments in the Advanced Graphite for
Lithium-Ion Batteries ..................................... 213
F.-X. Henry, I.V. Barsukov, J.E. Doninger, S. Anderson,
P.R. Booth, P.L. Zaleski, R.J. Girkant, D.J. Derwin,
M.A. Gallego, T. Huerta and G. Uribe
Mechanisms of Reversible and Irreversible Insertion in
Nanostructured Carbons Used for Li-lon Batteries .......... 231
F. Béguin, F. Chevallier, M. Letellier, C. Vix,
C. Clinard, J.N. Rouzaud and E. Frackowiak
Some Thermodynamics and Kinetics Aspects of
the Graphite-Lithium Negative Electrode for Lithium-Ion
Batteries ................................................. 245
R. Yazami, A. Martinent and Y. Reynier
Characterization of Anodes Based on Various Carbonaceous
Materials for Application in Lithium-Ion Cells ............ 259
A.N. Kozhevnikov, Y.A. Podalinski, O.R. Yakovleva,
V.S. Kotlyar, M.E. Petropavlovski, V.G. Smirnov and
V.V. Dzhurzha
A Carbon Composite for the Negative Electrode of Li-Ion
Batteries ................................................. 269
A.V. Churikov, N.A. Gridina and N.V. Churikova
Electrochemical Intercalation of PF6 and BF4 into
Single-Walled Carbon Nanotubes ............................ 277
R. Yazami, I.V. Goncharova and V.N. Plakhotnik
Surface Treated Natural Graphite as Anode Material for
High-Power Li-lon Battery Applications .................... 283
J. Liu, D. Vissers, K. Amine, I.B. Barsukov and
J.E. Doninger
Chapter 4:
Emerging Metal/Carbon Composite Anodes for Next Generation
Lithium-Ion Batteries ....................................... 293
Subject Overview .......................................... 295
On The Theoretical Prerequisites for Application of
Novel Materials in Promising Energy Systems ............... 297
V.Z. Barsukov and J.E. Doninger
Capabilities of Thin Tin Films as Negative Electrode
Active Materials for Lithium-Ion Batteries ................ 309
Y.O. Illin, V.Z. Barsukov and V.S. Tverdokhleb
Composite Anode Materials for High Energy Density
Lithium-Ion Batteries ..................................... 317
J.S. Gnanaraj, M.K. Gulbinska, J.F. DiCarlo,
I.V. Barsukov, N. Holt, V.Z, Barsukov and J.E. Doninger
Electrochemical Activity of Carbons Modified by d-Metal
Complexes with Ethanolamines .............................. 333
L.G. Reiter, V.A. Potaskalov, A.A. Andriiko,
V.S. Kublanovsky, M.A. Chmilenko, Y.K. Pirskiy,
V.I. Lisin and S.M. Chmilenko
Metal-Graphite Composites as Materials for Electrodes of
Lithium-Ion Batteries ..................................... 345
L. Matzui, M. Semen'ko, M. Babich and L. Kapitanchuk
Electrochemical Performance of Ni/Cu-Metallized &
Carbon-Coated Graphites for Lithium Batteries ............. 357
C.S. Johnson, K. Lauzze, N. Kanakaris, A. Kahaian,
M.M. Thackeray, K. Amine, G. Sandi-Tapia, S.A. Hackney
and R.O. Rigney
Chapter 5:
New Nano- Through Macro-Carbons for Energy Systems:
Synthesis, Modeling, Characterization ....................... 377
Subject Overview .......................................... 379
Stabilization of Graphite Nitrate via Co-intercalation
of Organic Compounds ...................................... 381
M.V. Savoskin, A.P. Yaroshenko, R.D. Mysyk and G.E. Whyman
Electrochemical Stability of Natural, Thermally
Exfoliated and Modified Forms of Graphite towards
Electrochemical Oxidation ................................. 389
I.O. Kovalenko, M.L. Barsukov, V.Z. Barsukov and
Y.V. Myshko
Low Temperature Synthesis of Graphite from Iron Carbide ... 399
S. Dimovski, A. Nikitin, H. Ye and Y. Gogotsi
High Resolution Transmission Electron Microscopy Image
Analysis of Disordered Carbons Used for Electrochemical
Storage of Energy ......................................... 411
J.-N. Rouzaud, C. Clinard, F. Chevallier, A. Thery and
F. Béguin
Electrolytes of Carbamide-Chloride Melts at Inert
Electrodes ................................................ 425
S.A. Kochetova and N.Kh. Tumanova
Graphite Intercalation as a Way to Carbon-Carbon
Composites and Carbon Nanoscrolls ......................... 433
M.V. Savoskin, A.P. Yaroshenko, V.N. Mochalin,
N.I. Lazareva and T.E. Konstantinova
Chapter 6:
Carbons in the Cathodes of Lithium-Ion Batteries;
Alternative Forms of MnO2, Cathode/Carbon Modeling .......... 441
Subject Overview .......................................... 443
Diagnostic Evaluation of Power Fade Phenomena and
Calendar Life Reduction in High-Power Lithium-Ion
Batteries ................................................. 445
R. Kostecki and F. McLarnon
Modeling of Electrochemical Processes in the Electrodes
Based on Solid Active Reagents and Conductive Carbon
Additives ................................................. 453
V.V. Matveyev
On the Optimal Design of Amorphous Mangaense Oxide For
Applications in Power Sources ............................. 473
S.A. Kirillov, T.V. Lesnichaya, N.M. Visloguzova,
S.A. Khainakov, O.I. Pendelyuk, D.I. Dzanashvili,
T.A. Marsagishvili, V.Z. Barsukov, V.G. Khomenko,
A.V. Tkachenko, and S.I. Chernukhin
Investigation of Cathodic Materials Based on Different
Types of MnO2/Carbon ...................................... 481
I.S. Makyeyeva, N.D. Ivanova, and G.V. Sokolsky
Investigation of Thin-Film Electrode Materials as
Cathodic Actives for Power Sources ........................ 487
N.E. Vlasenko, N.D. Ivanova, E.I. Boldyrev, and
O.A. Stadnik
Synthesis of Mixed Oxides using Polybasic Carboxylic
Hydroxy- and Amino-Acid Routes: Problems and Prospects .... 495
S.A. Kirillov, I.V. Romanova, and I.A. Farbun
Improved Electrochemical Properties of Surface-Coated
Li(Ni,Co,Mn)O2 Cathode Material for Li Secondary
Batteries ................................................. 505
S.H. Kang and K. Amine
Index ......................................................... 513
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