PROCEEDINGS OF THE WORKSHOP MEETING ON C1-C3
HYDROCARBON CONVERSION HELD IN KRASNOYARSK, USSR,
10-13 SEPTEMBER, 1991
Edited by A.G.Anshits (Krasnoyarsk, USSR) and
J.R.H.Ross (Limerick, Ireland)
Foreword vii
OXIDATIVE COUPLING AND PARTIAL OXIDATION OF METHANE
Catalysis and kinetics of oxidative methane coupling
H.Zanthoff, Z.Zhang, T.Grzybek, L.Lehmann and
M.Baerns (Bochum, Germany) 469
Free-radical reactions involved in C1-C3 hydrocarbons
interaction with oxide catalysts
O.V.Krylov (Moscow, USSR) 481
Hetero-homogeneous processes involved in oxidative
conversion of methane, ethane and hydrocarbon
mixtures over basic oxides
G.A.Martin (Villeurbanne, France), S.Bernal
(Cadiz, Spain), V.Pernchon and C.Mirodatos
(Villeurbanne, France) 487
Uncharged atomic oxygen in oxidative conversion of
C1-C2 alkanes
A.G.Anshits (Krasnoyarsk, USSR) 495
Catalyst and reactor requirements for the oxidative
coupling of methane
F.M.Dautzenberg, J.C.Schlatter (Mountain View,
CA, USA), J.M.Fox (San Francisco,CA, USA), J.R.
Rostrup-Nielsen and L.J.Christiansen
(Lyngby, Denmark) 503
Oxidative dehydrodimerization of methane on Bi-Mn
oxides: Catalyst active component and reaction
mechanism
I.V.Baidikova, A.E.Khalilov, V.P.Vislovsku,
E.A.Mamedov and R.G.Rizayev (Baku, Azerbaijan) 511
Active centres of magnesium oxide surface and
calculations of dissociative chemisorption of
methane on modified MgO
G.M.Zhidomirov and N.U.Zhanpeisov (Novosibirsk,
USSR) 517
Effect of pressure on the process of methane
oxidative dimenzation. Part 2: The catalyzed
reaction in conditions of suppression of the gas
phase reaction
Yu.P.Tulenin, A.A.Kadushin, V.A.Seleznev, A.F.
Shestakov and V.A.Menshikov (Moscow, USSR) 523
Transformations of the products of methane oxidative
coupling in the post-catalytic zone of the convertor
M.Taniewski, K.Skutil, R.Lachowicz, A.Lachowicz,
B.Dudek and D.Czechowicz (Gliwice, Poland) 529
Catalytic oxidative conversion of methane
L.N.Kurina, S.I.Galanov and L.Z.Meltser
(Tomsk, USSR) 537
Study on the active centers of methane coupling
catalysts by means of fluorescence emission of Eu3+
X.-G.Yang, Y.-L.Bi, K.-J.Zhen and Y.Wu
(Changchun, People's Republic of China) 543
IR spectroscopic analysis of isotopic C2
-products of the oxidative coupling of CH4+CD4
mixture over manganese oxide catalyst
Y.G.Borodko, L.M.Ioffe and A.Y.Borodko, Jr.
(Moscow, USSR) 549
Role of Li ion in Li-Mn-MgO catalyst for oxidative
coupling of methane
J.-J.Zhang, X.-G.Yang, Y.-L.Bi and K.-J.Zhen
(Changchun, People's Republic of China) 555
Effect of LiCl on molybdate based methane oxidation
catalysts
J.Kiwi, K.R.Thampi, N.Mouaddib and M.Gratzel
(Lausanne, Switzerland) 559
Elementary steps of radical-surface interactions in
oxidative coupling of methane
M.Yu.Sinev (Moscow, USSR) 561
Forming and redox properties of silica-supported Mn
catalysts of oxidative coupling of methane
Kh.M.Minachev, N.Ya.Usachev, E.P.Belanova and G.A.
Shirokova (Moscow, USSR) 565
The effect of electrochemical oxygen pumping on
catalytic properties of Ag and Au electrodes at
gas-phase oxidation of CH4
O.A.Mar'ina, V.A.Sobyanin, V.D.Belyaev and
V.N.Parmon (Novosibirsk, USSR) 567
Catalytic process of oxidative dimerization of methane
V.A.Menshchikov, P.S.Chekry and O.B.Shamrai
(Moscow, USSR) 571
Studies on the deactivation of P2O5-MgO/
RE2O3 catalyst for oxidative coupling of methane
W.-G.Xie, S.-J.Lu and F.-L.Qiu (Chengdu, People's
Republic of China) 575
Exchange isotope kinetics and activation mechanisms
of methane and oxygen on the oxide catalysts of
oxidative coupling of methane Sm203/MgO and Nd2O3/MgO
A.A.Shestov, V.S.Muzykantov (Novosibirsk, USSR),
Yu.P.Tyulenin and A.A.Kadushin (Moscow, USSR) 579
The Role of Structural Defects of CaO-catalysts in
the oxidative methane coupling
V.G.Roguleva, M.A.Nikiphorova, G.E.Selyutin,
V.P.Selina, A.I.Rubaylo and A.G.Anshits
(Krasnoyarsk, USSR) 581
The nature of the active phase in supported neodymium
catalysts for oxidative coupling of methane
M.Yu.Sinev, V.Yu.Bychkov, Yu.P.Tulenin,
O.V.Kalashnikova, B.V.Rozentuller and P.A.Shiryaev
(Moscow, USSR) 585
Effect of steam in the oxidative coupling of methane
over MgO and CaO based catalysts
O.V.Buyevskaya, M.P.Vanina, N.F.Saputina and
V.D.Sokolovskii (Novosibirsk, USSR) 589
Oxidative dehydrodimerization of methane over complex
oxide catalysts prepared by self-propagating high-
temperature synthesis
L.S.Marchenko, S.I.Zhuk, N.V.Kir'yakov,
M.D.Nersesyan and E.H.Grigoryan (Moscow, USSR) 593
Oxidative coupling of methane over vapour deposited
Sm2O3
E.Y.Gankina, G.S.Salitra and Y.G.Borodko
(Moscow, USSR) 595
Oxidative coupling of methane over natural manganese
oxide minerals
L.M.Ioffe and Y.G.Borodko (Moscow, USSR) 597
Oxidative coupling of methane over oxide catalysts
with layered structure
E.N.Voskresenskaya, L.I.Kurteeva, V.P.Zhereb and
A.G.Anshits (Krasnoyarsk, USSR) 599
A comparative study of coprecipitated BaCO3/La2On(CO3)m
catalysts for the oxidative coupling of methane
U.Olsbye, G.Desgrandchamps (Artix, France),
K.-J.Jens and S.Kolboe (Oslo, Norway) 603
Methane activation at elevated pressures in quartz
A.H.Weiss, J.-S.Tsaih (Worcester, MA, USA),
N.Davidova and M.Traykova (Sofia, Bulgaria) 609
Some features of methane oxidation at high pressures
V.I.Vedeneev, V.S.Arutyunov, N.Yu.Krymov
(Moscow, USSR), P.M.Cherbakov (Kharkov, USSR) and
A.D.Sedykh (Moscow, USSR) 613
Structure and performance of La2O3 promoted alkaline
earth oxide catalysts for the oxidative coupling
of methane
X.-R.Xia (Changchun, People's Republic of China),
W.Cui, G.-X.Xiong and X.-X.Quo (Dalian, People's
Republic of China) 617
Synergestic effect between NaCl and B2O3 in the NaCl/
B2O3/FeOx catalysts
for the oxidative coupling of methane
X.-R.Xia, (Changchun, People's Republic of China),
G.-X.Xiong and X.-X.Guo (Dalian, People's Republic
of China) 621
Oxidative dimerization of methane on lead containing
zeolites
N.Davidova, P.Kovacheva (Sofia, Bulgaria) and
A.H.Weiss (Worcester, MA, USA) 625
DEHYDROGENATION AND AROMATIZATION OF C1-C3 ALKANES
The effect of addition of a third component on the
behaviour of lithium doped magnesium catalysts used
for the oxidative dehydrogenation of ethane
H.M.Swaan, A.Toebes, K.Seshan, J.G. van Ommen
and J.R.H.Ross (Enschede, The Netherlands) 629
Activation of light alkanes over zeolite containing
systems
S.N.Khadzhiev, L.G.Agabalyan and I.M.Mamaeva
(Grozny, USSR) 635
Aromatization of ethane over modified pentasils
O.V.Chetina, T.V.Vasina, V.V.Lunin and O V Bragm
(Moscow, USSR) 639
Developments in aromatization of light alkanes
over pentasil zeolites
Kh.M.Minachev and A.A.Dergachev (Moscow, USSR) 645
Ethylene oligomenzation on phosphoric acid
S.N.Vereshchag, N.N.Shishkina, A.G.Anshits
(Krasnoyarsk, USSR) 651
Propane dehydrogenation over Pt-Sn catalysts
I.B.Yarusov, E.V.Zatolokina, N.V.Shitova,
A.S.Belyi and N M Ostrovskn (Omsk, USSR) 655
SELECTIVE OXIDATION AND AMMOXIDATION
Propane ammoxidation to acrylonitrile - An overview
G.Centi (Bologna, Italy), R.K.Grasselli (Washington,
DC, USA) and F.Tnfiro' (Bologna, Italy) 661
The partial oxidation of ethane to acetaldehyde
K.Otsuka, Y.Uragami and M.Hatano (Tokyo, Japan) 667
Catalytic (amm) oxidation of propane with molecular
oxygen over complex metal oxides: Involvement of
homogeneous reaction in gas phase
Y.-C.Kim, W.Ueda and Y.Moro-oka (Yokohama, Japan) 673
Oxidation of propane to acrylic acid
M.Ai (Yokohama, Japan) 679
Catalytic reactions of C1 and C3 hydrocarbons in
the presence of oxygen and oxygencontaining
compounds
S.V.Adelson, T.A.Vorontsova and O.V.Masloboy
shchikova (Moscow, USSR) 685
Methane oxidation by O3 under
mild conditions in the presence of iron supported
catalyst
A.M.Khenkin, V.S.Belova and M.L.Stepanova
(Chernogolovka, USSR) 689
IV.Some aspects of oxidative catalysis by supported
metal complexes (phtalocyanates of 3d-metals)
Yu.L.Zub, T.N.Yakubovich, A.B.Petcheny and
K.A.Kolesnikova (Kiev, USSR) 691
Photocatalytic reduction of carbon dioxide in aqueous
semiconductor suspensions
T.S.Dzhabiev, B.B.Tarasov and A.M.Uskov
(Chernogolovka, USSR) 695
Heat transfer control of selectivity in acetylene
hydrogenation
A.H.Weiss, J.-S.Tsaih (Worcester, MA USA),
G.V.Antoshin (Moscow, USSR), M.Kobayashi, A.Nakagawa
(Kitami, Japan), N.D.Tien and T.T.Tanh (Ho Chi
Minh City, South Vietnam) 697
Author index 699
Subject index 701
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