Organisation .................................................... v
Sponsors ....................................................... vi
Preface ....................................................... vii
Plenary Lectures
Advanced Coatings on High Temperature Applications
T. Narita, T. Izumi, T. Nishimoto, Y. Shibata, K. Zaini
Thosin and S. Hayashi ........................................ 1
Metal Dusting Reaction Mechanisms
D.J. Young .................................................. 15
I Fundamentals of High-Temperature Oxidation and Corrosion
High Temperature Passive Oxidation Mechanism of CVD SiC
T. Goto ..................................................... 27
Void Formation in Magnetite Scale Formed on Iron at 823
К -Elucidation by Chemical Potential Distribution-
M. Ueda, K. Kawamura and T. Maruyama ....................... 37
Transition from External to Internal Oxidation of Single
Phase Binary Alloys
Y.D. He, J. Ma, Z.W. Li and W. Gao .......................... 45
Behaviour of Copper and Nickel during High Temperature
Oxidation of Steel Containing Them
Y. Kondo .................................................... 53
Modern Analytical Techniques in High Temperature Oxidation
and Corrosion
M.J. Graham ................................................. 61
In Situ Study of Real Structure Effects on the Initial
Oxidation of FeCrAl Alloys by Two-Dimensional High
Temperature X-Ray Diffraction
P. Kodjamanova, H. Fietzek, M. Juez-Lorenzo, V. Kolarik
and H. Hattendorf ........................................... 69
Oxidation of a Low Carbon, Low Silicon Steel in Air at
600-920°C
R.Y. Chen and W.Y.D. Yuen ................................... 77
Micro-Area Analysis of the Corrosion Products Formed on Alloy
825 Exposed to Simulated Waste Incineration Boiler Conditions
A. Sato, H. Takahashi and M. Yoshiba ........................ 87
Gas-Tight Oxides - Reality or Just a Hope
C. Anghel, G. Hultquist, Q. Dong, J. Rundgren, I. Saeki
and M. Limbäck .............................................. 93
Phase Equilibria of the Nickel-Aluminium-Chromium System at
1150°C
Y. Kitajima, S. Hayashi and T. Narita ...................... 103
Initial Oxidation Rate Law of Binary Alloys by Hopping
Migration of Cations
I. Ishikawa and H. Nanjo ................................... 111
II Steam Oxidation and Influence of Hydrogen
Current Understanding of Steam Oxidation - Power Plant and
Laboratory Experience
S.R.J. Saunders and N.L. McCartney ......................... 119
The Role of Alloy Composition in the Steam Oxidation
Resistance of 9-12%Cr Steels
S. Osgerby and A.T. Fry .................................... 129
Effects of Hydrogen on the Corrosion Resistance of Metallic
Materials and Semiconductors
G. Hultquist, C. Anghel and P. Szakalos .................... 139
Beneficial Effect of Impurity Sulfur on High-Temperature
Steam Oxidation of High Chromium Ferritic Steels
Y. Murata, M. Nakai, K. Nagai, M. Morinaga, Y. Sasaki and
R. Hashizume ............................................... 147
The Effect of Gas Flow Rate on the Oxide Scale Morphology of
a 10%Cr-Ferritic Steels in Ar-H20 and Ar-H2-H20 Mixtures
J. Zurek, M. Michalik, L. Singheiser and W.J. Quadakkers ... 155
TDS Measurement of Hydrogen Released from Stainless Steel
Oxidized in H2O-Containing Atmospheres
A. Yamauchi, Y. Yamauchi, Y. Hirohata, T. Hino and
K. Kurokawa ................................................ 163
Effect of Chromium Content on the Oxidation Behaviour of
High-Speed Steels in Dry and Moist Air Environments
M.J. Monteiro and F.C. Rizzo .............................. 171
Steam Oxidation of TP 347H FG in Power Plants
A.N. Hansson and M. Montgomery ............................. 181
Hot Corrosion and Steam Oxidation Properties of New Heat
Resistant Steels for Ultra Super Critical Boilers
Y. Fukuda and M. Shimizu ................................... 189
The Relationship between High-Temperature Steam Oxidation
and Hydrogen Dissolution in High-Chromium Ferritic Steels
K. Nagai, M. Nakai, T. Kunieda, Y. Murata, M. Morinaga,
S. Matsuda and M. Kanno .................................... 197
Steam Oxidation Testing of Coatings for Next Generation
Steam Power Plant Components
A. Agьero, M. Gutierrez and R. Muelas ..................... 205
Corrosion Rate and Oxide Scale Characteristics of
Austenitic Alloys in Supercritical Water
Y. Watanabe and Y. Daigo ................................... 213
III Protective Coatings and Surface Treatments
Oxidation Behavior of Pt+Hf-Modified γ-Ni + γ'-Ni3А1 Alloys
T. Izumi and B. Gleeson .................................... 221
Early-Stage Oxidation Behavior of γ'-Ni3Аl-Based Alloys with
and without Pt Addition
S. Hayashi, T. Narita and B. Gleeson ....................... 229
2CaO*SiO2-CaO-ZrO2 Thermal Barrier Coating Formed by Plasma
Spray Process
N. Mifune and Y. Harada ................................... 239
Fundamental Coating Development Study to Improve the
Isothermal Oxidation Resistance and Thermal Cycle Durability
of Thermal Barrier Coatings
T. Torigoe, H. Oguma, I. Okada, G.C. Xu, K. Fujita,
A. Nakayama, T. Maruyama and K. Nishio ..................... 247
Preparation of High Oxidation-Resistant Surface by Molten
Salt Electrodeposition
M. Hara and M. Fukumoto .................................... 255
Strain Tolerance and Microstructure of Thermal Barrier
Coatings Produced by Electron Beam Physical Vapor Deposition
Process
K. Wada, Y. Ishiwata, N. Yamaguchi and H. Matsubara ........ 267
Wet Oxidation: a Promising Way for Fabrication of Zinc
Oxide Nanostructures
W. Gao and Z.W. Li ......................................... 277
Interdiffusion between Ni Based Superalloy and Diffusion
Barrier Coatings at 1423K
H. Matsumaru, S. Hayashi and T. Narita ..................... 285
Interdiffusion Behavior of Electroplated Platinum-Iridium
Alloys on Nickel-Base Single Crystal Superalloy TMS-82+
Y.N. Wu, A. Suzuki, H. Murakami and S. Kuroda .............. 293
Isothermal Oxidation of Pt Modified and Ru Modified
Aluminide Coating on a Fourth Generation Single Crystal
Superalloy
Y. Matsuoka, Y. Matsunaga, K. Nakagawa and S. Taniguchi .... 301
Development of an Oxidation Resistant Coating on Nb-Based
Ultra-High Temperature Alloy
K. Saito, S. Hayashi, T. Narita, I. Iwanaga and R. Tanaka .. 309
Oxidation Behavior of Ru-Containing Ni-Base Single-Crystal
Superalloys
К. Kawagishi, A. Sato, A. Sato, T. Kobayashi and
H. Harada .................................................. 317
Micro-/Nano-Crystal Aluminized ODS Coatings
Z.L. Zhan, Y.D. He, D. Wang and W. Gao ..................... 323
Novel Electrodeposited Ni-Based Nanocomposite Precursors for
Nitriding and Low Temperature Chromizing
X. Peng, J. Zhao, H. Zhang and F. Wang ..................... 331
Oxidation Property of CoNiCrAlY Coatings Prepared by Various
Thermal Spraying Techniques
M. Shibata, S. Kuroda, M. Watanabe and Y. Sakamoto ......... 339
In Situ Observation of Failure Behavior for Plasma Sprayed
Thermal Barrier Coating Systems under Static Loadings
S. Takahashi, M. Yoshiba, R. Kawamura and Y. Harada ........ 345
Environmental Effect of Hot Corrosion on Creep and Fatigue
Failure of Thermal Barrier Coating Systems
S. Takahashi, M. Yoshiba, W. Kakuta, S. Matsuoka and
Y. Harada .................................................. 353
Development of New Bond Coat System in Ni-Base Alloys
A. Sato, H. Harada and K. Kawagishi ........................ 361
Effect of Zirconium on Cyclic-Oxidation of Ni-40Cr-3Re
Alloys with α-Cr/β-NiAl Coatings
Y. Shibata, S. Hayashi and T. Narita ....................... 369
Formation of Ni Aluminide Layer Containing La by Molten-Salt
Electrodeposition and Cyclic-Oxidation Resistance
M. Fukumoto, M. Наrа and T. Narita ......................... 377
Effect of Laser Fusing on Hot Corrosion Resistance of Nickel
Based Self Fluxing Alloy Coating
Y. Li, K. Nishio, M. Katoh, T. Yamaguchi and S. Okamine .... 385
IV Mechanical and Chemical Aspects of Scale Adhesion
Mechanical Properties and Adherence of Oxide Scales
M. Schьtze, M. Malessa, D. Renusch, P.F. Tortorelli,
I.G. Wright and R.B. Dooley ................................ 393
The Effect of Oxide Scale on the Mechanical Behavior of Low
Alloyed Steel at High Temperature
J. Favergeon, G. Moulin, A. Makni and L. Lahoche ........... 401
Effect of Scale Microstructure on Scale Adhesion of Low
Carbon Sheet Steel
A. Kobayashi, K. Seto, T. Urabe, K. Yamada and K. Sato .... 409
Exfoliation and Fracture Behavior of Oxide Films Formed on
Titanium and Its Alloys in High Temperature Environments
Y. Isomoto Oka, T. Yamabe and T. Tsumura .................. 417
Interaction between Mechanical Loading in Creep and
Reactivity of Zirconium and Zircaloy at Temperature
G. Moulin, R.E. Tahhan, J. Favergeon, M. Viennot and
P. Berger .................................................. 425
Strains in Thermally Growing Alumina Films Measured In Situ
Using Synchrotron X-Rays
P.Y. Hou, A.P. Paulikas and B.W. Veal ...................... 433
Quantitative Adhesion Energy Values of Chromia-Rich Thermal
Oxides on Stainless Steels Determined by Blister and Tensile
Tests
A. Galerie, M. Dupeux, Y. Wouters and F. Toscan ............ 441
The Effects of Steel Composition on the Oxidation Kinetics,
Scale Structure and Scale-Steel Interface Adherence of Low
and Ultra-Low Carbon Steels
R.Y. Chen and W.Y.D. Yuen .................................. 451
Deformation and Fracture Behavior of Surface Oxide Scale on
Fe-13Cr Alloy in Hot-Rolling Process ]
Y. Hidaka, T. Anraku and N. Ohtsuka ........................ 461
Hardness of Oxide Scales on Fe-Si Alloys at Room- and
High-Temperatures i
T. Amano, M. Okazaki, Y. Takezawa, A. Shiino, M. Takeda,
T. Onishi, K. Seto, A. Ohkubo and T. Shishido .............. 469
Oxidation Behavior and Scale Properties of Si Containing
Steels
M. Takeda and T. Onishi .................................... 477
In Situ Growth-Stress Measurement of Cr2O3 Scale Formed on
Stainless Steels by Raman Spectroscopy
K. Kitamura, Y. Nishiyama, N. Otsuka and T. Kudo ........... 489
Effect of Cr Content and Water Vapor on Fracture Behavior of
the Scales Formed on Fe and Fe-Cr Alloy
K. Yanagihara, D. Renusch, M. Rцhrig and M. Schьtze ........ 497
Influence of Cooling Rate and Steel Composition on the Scale
Failure Characteristics during Cooling of Si-Containing Low
Carbon Steels
S. Taniguchi, Y. Hanamoto and J. Nakata .................... 505
V Corrosion in Incinerators and Metal Dusting
Development and Application of High Cr-High Si-Fe-Ni Alloys
to High Efficiency Waste- To-Energy Boilers
Y. Kawahara, K. Sasaki and Y. Nakagawa ..................... 513
Experiences with Inconel 625 in Biomass and Waste
Incineration Plants
M. Montgomery, O. Biede and O.H. Larsen .................... 523
Hot Corrosion Monitoring of Waste Incineration Corrosion
Processes Using Electrochemical Techniques
F.J. Perez, J. Nieto, J.A. Trilleros and M.P. Hierro ....... 531
Corrosivity of KCl(g) at Temperatures above Its Dew Point -
Initial Stages of the High Temperature Corrosion of Alloy
Sanicro 28 at 600°C
C. Pettersson, J.E. Svensson and L.G. Johansson ............ 539
Influence of Chlorine, Sulphur and Water Vapor on High
Temperature Corrosion of Fe, Cr, Ni Alloys for Waste
Incinerators
G. Moulin, K. Weulersse and J. Favergeon ................... 547
Effect of Alloying Elements on Corrosion Resistance of
Ni-Base Cast Alloys in Waste Incineration Environments
M. Noguchi, K. Matsuoka, H. Sakamoto, U. Shigeki and
Y. Sawada .................................................. 555
The Influence of Sulfur Additions on the Corrosive
Environments in a Waste-Fired CFB Boiler
J. Pettersson, С. Pettersson, N. Folkeson,
L.G. Johansson, E. Skog and J.E. Svensson .................. 563
An Overview of Metal Dusting in Synthesis Gas Environments
P. Szakдlos ................................................ 571
The Role of Copper in Resisting Metal Dusting of Ni-Base
Alloys
Y. Nishiyama and N. Otsuka ................................. 581
Numerical Analysis and Control of Gas Carburizing under
Changes in Gas Compositions
Y. Yokoyama, T. Mizukoshi, I. Ishigami and T. Usui ......... 589
VI Oxidation of Ceramics and Intermetallics
Microstructures of SiO2 Scales Formed on MoSi2
K. Kurokawa, D. Goto, J. Kuchino, A. Yamauchi,
T. Shibayama and H. Takahashi .............................. 595
Oxidation Rate of Magnesia-Carbon Refractory with Aluminium
Additive
H. Sunayama and M. Kawahara ................................ 603
ТЕМ Observation of the Initial Stage Oxidation of TiAl
Based Alloys in a Simulated Combustion Atmosphere
M. Yoshihara, S. Taniguchi and X.Y. Li ..................... 609
Influence of the Third Element on the High Temperature
Oxidation Behavior of γ'-Ni3Al Alloys
S. Mikuni, S. Hayashi and T. Narita ........................ 617
Influence of Additional Elements on the Oxidation Behaviour
of Nb-Al-Cr Base Alloys
S. Taniguchi, H. Tanaka and T. Maeda ....................... 625
Influence of Ion Implantation of Several Elements on
Oxidation Behavior of TiAl
M. Yoshihara, S. Taniguchi, D. Furumaki and M. Aono ........ 633
Isothermal Oxidation of Sintered β-FeSi2 in Air
M. Nanko, S.H. Chang, K. Matsumaru, K. Ishizaki and
M. Takeda .................................................. 641
High Temperature Oxidation of TiAl-1.5wt.%Mn-
(0,5,10)wt.%Y2O3 Alloys
D.B. Lee ................................................... 649
Microstructure and Oxidation of Al/BN Composites Fabricated
by the Pressureless Infiltration Method
D.B. Lee ................................................... 657
Effect of Coatings on the Creep and Oxidation Behavior of
TiAl Alloys at 1173K in Air
T. Nishimoto, S. Hayashi and T. Narita ..................... 665
Author Index .................................................. 673
Keyword Index ................................................. 677
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