Muñoz A.G. Photoelectrochemical solar conversion systems: molecular and electronic aspects. - Boca Raton: CRC Press/Taylor & Francis, 2013. - xi, 336 p.: ill. - Incl. bibl. ref. - Ind.: p.331-336. - ISBN 978-1-4398-6925-3  Место хранения:   026 | Институт физики полупроводников СО РАН | Новосибирск | Библиотека

Оглавление / Contents

Preface ....................................................... vii About the Author ............................................... xi Chapter 1 Principles and Systems in Light-Induced Energy Conversion ...................................................... 1 1.1 Basic Aspects of Light-Induced Generation of Fuels ......... 1 1.2 Development of Energy Conversion Systems .................. 12 1.3 Advanced Concepts for Sunlight Energy Conversion .......... 21 1.4 Inorganic Concepts ........................................ 26 1.5 Energy and Electron Transfer Processes .................... 33 References ..................................................... 44 Chapter 2 Nanodimensioned Systems Based on Semiconductor- Pxide-Metal-Electrolyte Contacts ............................... 53 2.1 Fundamentals of Electrochemical Phase Formation ........... 53 2.2 Experimental Techniques and Experiment Designs ............ 63 2.3 The Electrodeposition of Selected Systems ................. 69 2.3.1 Electrodeposition of Indium ........................ 70 2.3.2 Electrodeposition of Co onto Silicon ............... 74 2.3.3 Electrocrystallization of Noble Metals onto Silicon ............................................ 82 2.3.4 Elecrodeposition onto Niobium Oxide ................ 89 2.4 Anodic Oxide Growth: Mechanisms, Methods, and Properties .. 95 References .................................................... 133 Chapter 3 Physics of Electrolyte-Metal-Oxide-Semiconductor (EMOS) Contacts in Nanodimensions ............................. 143 3.1 The Electron Transfer in Nanodimensioned Schottky Contacts ................................................. 143 3.2 Analysis of Complex Systems: The EMOS Interface .......... 153 References .................................................... 179 Chapter 4 Electrocatalysis on Nanodimensioned EMOS Contacts .. 183 4.1 Fundamental Aspects of the Metal-Electrolyte Interface ... 183 4.2 The Electron Transfer at Metal-Electrolyte Interfaces: From Butler-Volmer to Quantum Mechanical Concepts ........ 197 4.3 Reaction Mechanisms in Selected Systems: Hydrogen Evolution and CO2 Reduction .............................. 203 4.4 Development of New Electrochemical Catalysts: Future Directions ............................................... 230 References .................................................... 235 Chapter 5 Electronics and Chemistry of Electrolyte-Metal- Oxide-Semiconductor Contacts .................................. 243 5.1 Methods: Combination of Electrochemical Techniques with Surface-Sensitive Spectroscopy ...................... 243 5.2 Chemical and Electronic Properties of Electrochemical Generated Interfaces on Silicon .......................... 257 5.3 Modulation of the Interfacial Potential in Nanodimensioned EMOS Contacts ............................ 294 References .................................................... 301 Chapter 6 Optical Effects: Current Approaches and Future Directions .................................................... 307 References .................................................... 326 Index ......................................................... 331