Silicon chemistry: from the atom to extended systems / ed. by P.Jutzi, U.Schubert. - Weinheim; Cambridge: Wiley-VCH, 2003. - xi, 494 p.: ill. - Ind.: p.489-494. - ISBN 3-527-30647-1  Место хранения:   024 | Институт неорганической химии им. А.В.Николаева CO РАН | Новосибирск

Оглавление / Contents

I Reactive Intermediates in Silicon Chemistry - Synthesis, Characterization, and Kinetic Stabilization Introduction .................................................... 1 P. Jutzi, U. Schubert Investigations on the Reactivity of Atomic Silicon: A Playground for Matrix Isolation Spectroscopy .................. 4 G. Maier, H. P. Reisenauer, H. Egenolf, J. Glatthaar Reactions with Matrix Isolated SiO Molecules ................... 20 H. Schnöckel, R. Köppe In situ - Diagnostics of Amorphous Silicon Thin Film Deposition ..................................................... 33 H. Stafast, G. Andrä, F. Falk, E. Witkowicz The Gas Phase Oxidation of Silyl Radicals by Molecular Oxygen: Kinetics and Mechanism ................................. 44 T. Köcher, С. Kerst, G. Friedrichs, F. Temps Oxidation of Matrix-Isolated Silylenes ......................... 58 W. Sander, H. F. Bettinger, H. Bornemann, M. Trommer, M. Zielinski Short-Lived Intermediates with Double Bonds to Silicon: Synthesis by Flash Vacuum Thermolysis, and Spectroscopic Characterization ............................................... 71 H. Beckers Kinetic Stabilization of Disilenes >Si=Si< and Disilynes -Si≡Si- ........................................................ 85 N. Wiberg A Tetrasilabuta-l,3-diene and Related Compounds with Conjugated Multiple Bonds ..................................... 100 M. Weidenbruch II Si-Si-Systems: From Molecular Building Blocks to Extended Networks Introduction .................................................. 115 P. Jutzi, U. Schubert Chemistry of Metalated Oligosilanes ........................... 118 R. Fischer, D. Frank, C. Kayser, C. Mechtler, J. Baumgartner and C. Marschner Oligosilyl Substituted Heptaphosphanes - Syntheses, Reactions and Structures ...................................... 129 J. Baumgartner, V. Cappello, A. Dransfeld, К. Hassler Polysilanes: Formation, Bonding and Structure ................. 139 R.G. Jones Phase Behavior of n-Alkylsubstituted Polysilanes .............. 159 C. Mueller, C. Peter, H. Frey, С. Schmidt Structural and Electronic Systematics in Zintl Phases of the Tetrels ....................................................... 171 R. Nesper Zintl Phases MSi2 (M = Ca, Eu, Sr, Ba) at Very High Pressure .. 181 J. Evers, G. Oehlinger Silicon- and Germanium-Based Sheet Polymers and Zintl Phases .. 194 M.S. Brandt, G. Vogg, M. Stutzmann Kautsky-Siloxene Analogous Monomers and Oligomers ............. 214 H. Stüger Silicon-Based Nanotubes: A Theoretical Investigation .......... 226 Th. Köhler, G. Seifert, Th. Frauenheim Structure and Reactivity of Solid SiO ......................... 242 U. Schubert, T. Wieder Si Nanocrystallites in SiOx Films by Vapour Deposition and Thermal Processing ............................................ 252 H. Hofmeister, U. Kahler Theoretical Treatment of Silicon Clusters ..................... 269 A. Sax Isomers of Neutral Silicon Clusters ........................... 281 R. Schäfer, M.I Rosemeyer, С. Herwig, J.A. Becker Investigation of the Influence of Oxidation and HF Attack on the Photoluminescence of Silicon Nanoparticles ................ 293 F. Huisken, G. Ledoux, O. Guillois, C. Reynaud Localization Phenomena and Photoluminscence from Nano- structured Silicon, Silicon/Silicon Dioxide Nanocomposites, Silsesquioxanes and Branched Polysilanes ...................... 308 S. Veprek, D. Azinovic III Si-O Systems: From Molecular Building Blocks to Extended Networks Introduction .................................................. 321 P. Jutzi, U. Schubert Higher-Coordinate Silicon Compounds with SiO5 and SiO6 Skeletons: Syntheses and Crystal Structures ................... 324 R. Таске, О. Seiler Functionalized Silanols and Silanolates ....................... 338 S. Kliem, C. Reiche, and U. Klingebiel Transition Metal Fragment Substituted Silanols of Iron and Tungsten - Synthesis, Structure and Condensation Reactions .... 348 W. Malisch, M. Hofmann, M. Vögler, D. Schumacher, A. Sohns, H. Bera, H. Jehle Rational Syntheses of Cyclosiloxanes and Molecular Alumo- and Gallosiloxanes ............................................ 360 M.l Veith, A. Rammo Synthesis, Structure and Reactivity of Novel Oligomeric Titanasiloxanes ............................................... 372 P. Jutzi, H. M. Lindemann, J.-О. Nolte, M. Schneider Metallasilsesquioxanes - Synthetic and Structural Studies ..... 383 F.T. Edelmann Spin-Spin Interaction in Silsesquioxanes and Transition Metal Substitution ............................................ 395 W.W. Schoeller, D. Eisner Characterization of Si-polymers by Coupling of HPLC- Separation Methods with MALDI-TOF-MS .......................... 406 J. Falkenhagen, R.-P. Krüger, G. Schulz The Stepwise Formation of Si-O-Networks ....................... 419 M. Binnewies, N. Söger Mechanism of Ring and Cage Formation in Siloxanes ............. 431 KUug Structurally Well-Defined Amphiphilic Polysiloxane Copolymers .................................................... 439 G. Kickelbick, J. Bauer, N. Hüsing Synthesis and Functionalization of Mesostructured Silica-Based Films ............................................ 451 N. Hüsing, В. Launay, G. Kickelbick Modification of Ordered Mesostructured Materials during Synthesis .................................................... 460 S. Altmaier, P. Behrens Biosilicification; Structure, Regulation of Structure and Model Studies ................................................ 475 С.C. Perry Subject Index ................................................ 489