Reagents for silicon-mediated organic synthesis / ed. by Ph.L.Fuchs. - Chichester: John Wiley & Sons Inc, 2011. - xi, 822 p.: ill. - (Handbook of reagents for organic synthesis). - Incl. bibl. ref. and indexes. - ISBN 978-0-470-7-1023-4  Место хранения:   032 | Институт органической химии им. Н.Н.Ворожцова СО РАН | Новосибирск | Библиотека

Оглавление / Contents

Introduction ................................................... xv Reagent Finder Table ........................................ xxiii Short Note on InChls and InCMKeys ............................ xxxi 3-Acetoxy-2-trimethylsilylmethyl-1-propene ...................... 1 Allyl(2-chloroethyl)dimethylsilane .............................. 9 AUyl Trichlorosilane ........................................... 10 Allyltrimethylsilane ........................................... 14 Allyltrimethylsilylzinc Chloride ............................... 24 Ammonium Hexafluorosilicate .................................... 25 Azidotrimethylsilane ........................................... 26 Benzene, [[Difluoro(trimethylsilyl)methyl]seleno] .............. 33 Benzene, [[Difluoro(trimethylsilyl)methyl]thio]- ............... 36 Benzene, [[(1E)-2-(Trimethylsilyl)ethenyl]seleno] .............. 39 Benzene, [[(1E)-2-trimethylsilyl)ethenyl]sulfonyl]- ............ 42 2,1-Benzoxasilole,1,3-Dihydro-1,1-dimethyl- .................... 43 N-Benzyl-N-(methoxymethyl)-N-trimethylsilylmethylamine ......... 44 1,2-Bis(t-butyldimethylsilyl)hydrazine ......................... 46 1,2-Bis(chlorodimethylsilyl)ethane ............................. 48 1,4-Bis(dimethylamino)-1,1,4,4-tetramethyldisilethylene ........ 50 Bis(1-methoxy-2-methyl-1-propenyloxy)dimethylsilane ............ 51 Bis(methylthio)(trimethylsilyl)methane ......................... 52 [Bis(2-pyridyldimethylsilyl)methyl]lithium ..................... 54 1.3-Bis(triisopropylsilyl)propyne .............................. 56 N,O-Bis(trimethylsilyl)acetamide ............................... 58 (1E,3E)1,4-Bis(trimethylsilyl)-1,3-butadiene ................... 73 Bis(β-trimethylsilylethanesulfonyl)imide ....................... 74 N,O-Bis(trimethylsilyl)hydroxylamine ........................... 75 Bis[(trimethylsilyl)methyl]zinc ................................ 76 Bis(trimethylsilyl) Peroxide ................................... 79 Bis(trimethylsilyl) Selenide ................................... 82 Bis(trimethylsilyl) Sulfide .................................... 83 Bromomagnesium Hexamethyldisilazide ............................ 85 (Bromomethyl)chlorodimethylsilane .............................. 85 Bromotrimethylsilane ........................................... 92 (E)-1-Bromo-4-trimethylsilyl-1-buten-3-yne .................... 100 (Z)-2-Bromo-1-(trimethylsilyloxy)ethylene ..................... 105 2-Bromo-3-trimethylsilyl-1-propene ............................ 106 (l-Bromovinyl)trimethylsilane ................................. 109 t-Butyldimethylchlorosilane ................................... 110 t-Butyldimethylsilyl Cyanide .................................. 120 (t-Butyldimethylsilyl)diphenylphosphine ....................... 121 2-t-Butyldimethylsilyl-1,3-dithiane ........................... 122 O-(t-Butyldimethylsilyl)hydroxylamine ......................... 124 N-(t-Butyldimethylsilyl)-N-methyltrifluoroacetamide ........... 125 t-Butyldimethylsilyl Trifluoromethanesulfonate ................ 127 t-Butyldiphenylchlorosilane ................................... 135 1-t-Butylthio-1-t-butyldimethyl-silyloxyethylene .............. 138 1-t-Butylthio-1-t-butyldimethylsilyloxypropene ................ 141 t-Butyl Trimethylsilylacetate ................................. 147 3-Butyn-2-ol,4-(Trimethylsilyl)- .............................. 148 Chlorodii sopropylsilane ...................................... 151 Chlorodimethylsilane .......................................... 156 Chlorodimethylvinylsilane ..................................... 157 Chlorodiphenylsilane .......................................... 162 (Chloromethyl)dimethylphenylsilane ............................ 162 (E)-(3-Chloro-1-methyl-1-propenyl)-trimethylsilane ............ 166 1-Chloro-1-methylsiletane ..................................... 166 Chlorotrimethylsilane ......................................... 170 Chlorotriphenylsilane ......................................... 182 Cyanotrimethylsilane .......................................... 184 Diazo(trimethylsilyl)methyllithium ............................ 191 (Dibromomethyl)trimethylsilane ................................ 197 Di-t-butylchlorosilane ........................................ 198 Dw-butyldichlorosilane ........................................ 201 trans-1,1-Di-t-butyl-2,3-dimethylsilirane ..................... 207 Di-t-butylsilyl Bis(trifluoromethanesulfonate) ................ 209 Dichlorodiisopropylsilane ..................................... 222 Dichlorodimethylsilane ........................................ 228 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane ................. 230 1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane ................. 233 Dicyanodimethylsilane ......................................... 234 1,2-Diethoxy-1,2-bis(trimethylsilyloxy)ethylene ............... 235 N,N-Diethylaminodimethylsilane ................................ 237 Diethyl[dimethyl(phenyl)silyl]aluminum ........................ 237 Diiododimethylsilane .......................................... 238 Diisopropyl Chlorosilane, Polymer-supported ................... 240 Diisopropylsilyl Bis(trifluoromethanesulfonate) ............... 241 Dilithium Cyanobis(dimethylphenylsilyl)-cuprate ............... 248 (α,α-Dimethylallyl)trimethylsilane ............................ 252 (2-Dimethylaminomethylphenyl)phenylsilane ..................... 253 Dimethyl(phenyl)silane ........................................ 254 Dimethylphenylsilyllithium .................................... 255 1,1-Dimethylsilacyclobutane ................................... 261 Dimethylthexylsilyl Chloride .................................. 263 Dimethylthexylsilyl Trifluoromethanesulfonate ................. 265 1,3,2-Dioxaborolane,2-(Dimethylphenylsilyl)-4,4,5,5- tetramethyl-,1,3,2-Dioxaborolane,4,4,5,5-Tetramethyl- 2-(methyldiphenylsilyl)-,1,3,2-Dioxaborolane,4,4,5,5- Tetramethyl-2-(triphenylsilyl)- ............................... 270 Diphenyldifluorosilane ........................................ 276 Disilane,1,1,1,2,2,2-hexamethyl- .............................. 278 1-Ethoxy-1-(trimethylsilyloxy )cyclopropane ................... 285 Ethoxy(trimethylsilyl)acetylene ............................... 289 Ethyl Lithio(trimethylsilyl)acetate ........................... 293 Ethyl (Methyldiphenylsilyl)acetate ............................ 295 Ethyl 2-(Methyldiphenylsilyl)propanoate ....................... 296 Ethyl Trimethylsilylacetate ................................... 297 Fluorosilicic Acid ............................................ 301 Formamide, AWV, bis(trimethylsilyl)- .......................... 302 Hexachlorodisilane ............................................ 309 Hexamethylcyclotrisiloxane .................................... 310 Hexamethyldisiloxane .......................................... 313 Hexamethyldisilazane .......................................... 317 (Iodoethynyl)trimethylsilane .................................. 321 (Iodomethyl)trimethylsilane ................................... 323 Iodotrimethylsilane ........................................... 325 (E)-1-Iodo-3-trimethylsilyl-2-butene .......................... 336 3-Iodo-2-trimethylsilylmethyl-1-propene ....................... 338 Isocyanatotrimethylsilane ..................................... 339 Ketene t-Butyldimethylsilyl Methyl Acetal ..................... 341 3-1ithio-1-triisopropylsilyl-1-propyne ........................ 347 Lithium N-Benzyltrimethylsilylamide ........................... 349 Lithium Bis[dimethyl(phenyl)silyl]cuprate ..................... 350 Lithium Cyano(dimethylphenylsilyl)cuprate ..................... 353 Lithium Hexamethyldisilazide .................................. 356 Methanamine,1,1-Bis(trimethylsilyl) ........................... 369 Methanesulfonamide,1,1,1-Trifluoro-N[(trifluoromethyl) sulfonyl]-N(trimethylsilyl)- .................................. 372 (Methoxymethyl)bis(trimethylsilyl)amine ....................... 374 1-Methoxy-2-methyl-1-(trimethylsilyloxy)propene ............... 376 N-Methyl-N,O-bis(trimethylsilyl)-hydroxylamine ................ 380 Methyldiphenylchlorosilane .................................... 381 (Methylthio)trimethylsilane ................................... 388 Methyltrichlorosilane ......................................... 389 Methyl Trichlorosilyl Ketene Acetal (1) ....................... 393 Methyl 2-Trimethylsilylacrylate ............................... 396 1-Methyl-1-(trimethylsilyl)allene ............................. 397 2-Methyl-2-(trimethylsilyloxy)-3-pentanone .................... 400 PDMS Thimbles ................................................. 403 Phenylsilane-Cesium Fluoride .................................. 408 (2-Phenylsulfonylethyl)trimethylsilane ........................ 409 Phenylthiobis(trimethylsilyl)methane .......................... 411 (Phenylthiomethyl)trimethylsilane ............................. 412 (Phenylthio)trimethylsilane ................................... 414 1-(Phenylthio)-1-(trimethylsilyl)cyclopropane ................. 418 1-Phenylthio-1-trimethylsilylethylene ......................... 419 2-(Phenylthio)-2-(trimethylsilyl)propane ...................... 420 Phenyl Trimethylsilyl Selenide ................................ 421 Phosphine, Tris(trimethylsilyl)- .............................. 422 Polymethylhydrosiloxane ....................................... 427 Potassium Hexamethyldisilazide ................................ 432 (+)-9-(1S,2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)- 9-borabicyclo[3.3.2]decane .................................... 453 2-Pyridyldimethylsilane ....................................... 457 Silane, l,l'-(Chloromethylene)bis[l,l,l]-trimethyl- ........... 461 Silane, Chlorotri-2-propen-1-yl- .............................. 463 Silane, 1,l'-(1-Propene-1,3-diyl)bis[1,1,l-trimethyl- (E) Silane, 1,1'-(1-Propene-1,3-diyl)bis [1,1,1-trimethyl- (Z) Silane, 1,1'-(1-Propene-1,3-diyl)bis [1,1,1- trimethyl-(E+Z) ............................................... 464 Sodium Hexamethyldisilazide ................................... 468 Tetrabutylammonium Difluorotriphenylsilicate .................. 479 2,4,6,8-Tetraethenyl-2,4,6,8-tetramethyl- cyclotetrasiloxane ............................................ 484 3-Tetrahydropyranyloxy-1-trimethylsilyl-1-propyne ............. 487 1,1,3,3-Tetramethyldisilazane ................................. 488 1,1,2,2-Tetraphenyldisilane ................................... 490 Trialkylsilyl Cyanide, Polymer-supported ...................... 494 Tribenzylchlorosilane ......................................... 496 Tri(f-butoxy)silanethiol ...................................... 497 (E)-1-Tri-n-butylstanny 1-2-trimethylsilylethylene ............ 499 Trichloroiodosilane ........................................... 500 Triethoxy silane .............................................. 501 Triethylsilane ................................................ 506 Triethylsilyl Нydrotrioxide ................................... 514 3-Triethylsilyloxy-1,4-pentadiene ............................. 515 (α-Triethylsilyl)propionaldehyde Cyclohexylimine .............. 516 Triethylsily 1 Trifluoromethanesulfonate ...................... 517 Trimethylsilyl Trifluoromethanesulfonate ...................... 518 Trifluoromethanesulfonic Acid, Chlorobis(1,1-Dimethylethyl) silyl Ester ................................................... 537 Trifluoromethyltrimethylsilane ................................ 539 Triisopropylsilanethiol ....................................... 546 (Triisopropylsilyl)acetylene .................................. 550 Triisopropylsilyl Chloride .................................... 554 Triisopropylsilylethynyl Triflone ............................. 558 Triisopropylsilyl Trifluoromethanesulfonate ................... 559 Trimethylsilylacetic Acid ..................................... 562 Trimethylsilylacetone ......................................... 563 Trimethylsilylacetonitrile .................................... 564 Trimethylsilylacetylene ....................................... 569 (Trimethylsilyl)allene ........................................ 580 Trimethylsilylallyllithium .................................... 582 (E)-1-Trimethylsilyl-1,3-butadiene ............................ 585 3-Trimethylsilyl-3-buten-2-one ................................ 586 9-[1-(Trimethylsilyl)-2(E)-butenyl]-9-borabicyclo[3.3.1] nonane ........................................................ 588 Trimethylsilylcopper .......................................... 589 Trimethylsilyldiazomethane .................................... 590 Trimethylsilyldiethylamine .................................... 598 2-Trimethylsilyl-1,3-dithiane ................................. 604 2-(Trimethylsilyl)ethanesulfonamide ........................... 609 β-Trimethylsilylethanesulfonyl Chloride ....................... 611 [N-(2-(Trimethylsilyl)ethanesulfonyl)-imino]phenyliodane ...... 617 2-(Trimethylsilyl)ethanethiol ................................. 618 2-(Trimethylsilyl)ethanol ..................................... 622 2-(Trimethylsilyl)ethoxycarbonylimidazole ..................... 627 2-(Trimethylsilyl)ethoxymethyl Chloride ....................... 628 [2-(Trimethylsilyl)ethoxymethyl]triphenylphosphonium Chloride ...................................................... 633 2-(Trimethylsilyl)ethyl Chloroformate ......................... 634 2-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1- carboxylate ................................................... 636 (Trimethylsilyl)ethynylcopper(I) .............................. 637 Trimethylsilyl Fluorosulfonyldifluoroacetate .................. 638 N-(Trimethylsilyl)imidazole ................................... 640 Trimethylsilylketene .......................................... 645 Trimethylsilyllithium ......................................... 650 Trimethylsilyl Methanenitronate ............................... 653 1 -Trimethylsilyl-1-methoxyallene ............................. 656 Trimethylsilylmethyl Azide .................................... 657 1-[(Trimethylsilyl)methyl]-1H-benzotriazole ................... 658 2-Trimethylsilylmethyl-1,3-butadiene .......................... 660 3-[(Trimethylsilyl)methyl]-3-butenoic Acid Methyl Ester ....... 662 Trimethylsilylmethyllithium ................................... 664 Trimethylsilylmethylmagnesium Chloride ........................ 666 Trimethylsilylmethylpotassium ................................. 674 2-Trimethylsilylmethyl-2-propen-1-ol .......................... 675 1-Trimethylsilyloxy-1,3-butadiene ............................. 677 2-Trimethylsilyloxy-1,3-butadiene ............................. 681 2-Trimethylsilyloxyfuran ...................................... 684 (Z)-2-(Trimethylsilyloxy)vinyllithium ......................... 693 5-Trimethylsilyl-1,3-pentadiene ............................... 695 2-(Trimethylsilyl)phenyl Triflate ............................. 697 Trimethylsilylpotassium ....................................... 700 2-Trimethylsilyl-1,3-propanediol .............................. 701 3-Trimethylsilyl-2-propen-1-yl Acetate ........................ 703 3-Trimethylsilyl-1-propyne .................................... 704 3-Trimethylsilyl-2-propynylcopper(I) .......................... 711 2-(Trimethylsilyl)thiazole .................................... 712 Trimethylsilyltributylstannane ................................ 719 3-Trimethylsilyl-3-trimethylsilyloxy-1-propene ................ 723 (E)-1-Trimethylsilyl-2-trimethylstannylethylene ............... 724 (Trimethylsilyl)vinylketene ................................... 725 1-(Trimethylsilyl)vinyllithium ................................ 726 (E)-2-(Trimethylsilyl)vinyllithium ............................ 729 1 -(Trimethylsilyl) vinylmagnesium Bromide-Copper(I) Iodide ... 730 Trimethyl {2-[(tributylstannyl)methyl]-2-propenyl} silane ..... 731 Triphenylsilane ............................................... 733 Tris(dimethylamino)sulfonium Difluorotrimethylsilicate ........ 739 Tris(trimethylsilyl)aluminum .................................. 745 Tris(trimethylsilyl)methane ................................... 746 Tris(trimethylsilyl)silane .................................... 747 Vinyltrimethylsilane .......................................... 755 List of Contributors .......................................... 763 Reagent Formula Index ......................................... 779 Subject Index ................................................. 785