Sliwa W. Calixarenes and resorcinarenes: synthesis, properties and applications / W.Sliwa, C.Kozlowski. - Weinheim: Wiley-VCH, 2009. - vii, 316 p.: ill. - Incl. bibl. ref. - Ind.: p.305-316. - ISBN 978-3-527-32263-3  Место хранения:   024 | Институт неорганической химии им. А.В.Николаева CO РАН | Новосибирск

Оглавление / Contents

1 Introduction ................................................. 1 Part I General Characteristics of Calixarenes .................. 5 1 Reactivity of Calixarenes .................................... 7 1.1 Functionalization of the Narrow Rim ..................... 7 1.2 Functionalization of the Wide Rim ...................... 12 1.3 Functionalization of Both Rims ......................... 27 1.4 Bridging of Calixarenes ................................ 32 2 Physicochemical Properties of Calixarenes ................... 43 2.1 Selected Physicochemical Properties of Calixarenes ..... 43 2.2 Crystallographic Studies of Calixarenes ................ 48 2.3 Calculations of Calixarene Structures .................. 55 3 Chiral Calixarenes .......................................... 57 4 Calixarene Assemblies ....................................... 65 5 The Role of Calixarenes in Biological Processes ............. 69 5.1 Antibacterial and Antiviral Calixarenes ................ 69 5.2 Transmembrane Systems of Biologically Active Calixarenes ............................................ 70 5.3 Calixarenes Binding Proteins, Nucleotides, and Nucleic Acids .......................................... 73 5.4 Calixarenes of Other Biological Activities ............. 78 6 Applications of Calixarenes ................................. 81 6.1 Calixarene Sensors ..................................... 81 6.2 Calixarene Catalysts ................................... 84 6.3 Nanoparticles Coated with Calixarenes .................. 86 6.4 Other Applications of Calixarenes ...................... 90 References .................................................. 93 Part II Inclusion Complexes of Calixarenes and Calixcrowns .... 101 7 Inclusion Complexes of Calixarenes with Neutral and Charged Species ............................................ 103 7.1 Inclusion Complexes of Calixarenes with Neutral Molecules ............................................. 103 7.1.1 Inclusion Complexes of Calix[4]arene ........... 103 7.1.2 Inclusion Complexes of Higher Calixarenes ...... 110 7.2 Inclusion Complexes of Calixarenes with Anions ........ 114 7.2.1 Calixarene Chromogenic Sensors for Anions ...... 114 7.2.2 Calixarene Fluorescent Sensors for Anions ...... 116 7.2.3 Ion Selective Electrodes for Anions ............ 122 7.3 Inclusion Complexes of Calixarenes with Ion Pairs ..... 124 7.4 Inclusion Complexes of Calixarenes with Cations ....... 126 7.5 Inclusion Complexes of Calixarenes with Fullerenes .... 128 7.6 Inclusion Complexes of Calixarenes with Gases ......... 132 8 Inclusion Complexes of Calixarenes with Metal Ions ......... 135 8.1 Inclusion Complexes of Calixarenes with Alkali and Transition Metal Ions ................................. 135 8.2 Inclusion Complexes of Calixarenes with Lanthanides and Actinides ......................................... 141 8.3 Use of Calixarenes in the Solvent Extraction of Metal Ions ............................................ 148 8.4 Calixarenes as Sensors for Metal Ions ................. 154 8.5 Calixarene Metal Complexes as Catalysts ............... 157 9 Inclusion Complexes of Calixcrowns with Metal Ions ......... 165 9.1 Inclusion Complexes of Calixcrowns with Alkali Metal Ions .................................................. 165 9.2 Use of Calixcrowns in the Solvent Extraction of Metals ................................................ 167 9.3 Calixcrowns as Sensors for Metal Ions ................. 171 References ................................................. 175 Part III Supramolecular Calixarene Structures and Related Systems ....................................................... 181 10 Cavitands .................................................. 183 10.1 Simple Cavitands ...................................... 183 10.2 Deep Cavitands ........................................ 189 11 Capsules ................................................... 201 11.1 Calixarene-Based Capsules ............................. 201 11.1.1 Homodimeric Capsules ........................... 201 11.1.2 Heterodimeric Capsules ......................... 204 11.2 Cavitand-Based Capsules ............................... 215 11.2.1 Dimeric Capsules Formed from Simple Cavitands ...................................... 215 11.2.2 Dimeric Capsules Formed from Deep Cavitands .... 224 11.2.3 Hexameric Capsules ............................. 231 12 Calixarene Nanotubes and Helices ........................... 237 12.1 Calixarene Nanotubes .................................. 237 12.2 Calixarene Helices .................................... 243 13 Calixarene Supramolecular Assemblies ....................... 247 13.1 Calixarene Assemblies with TTF Units .................. 247 13.2 Calixarene Assemblies with Polymers ................... 248 13.3 Calixarene Molecular Machines ......................... 250 13.4 Calixarene Molecular Actuators ........................ 252 References ................................................. 253 Part IV Resorcinarenes ........................................ 257 14 Resorcinarenes ............................................. 259 14.1 Synthesis of Resorcinarenes ........................... 259 14.2 Reactivity of Resorcinarenes .......................... 264 14.3 Physicochemical Properties of Resorcinarenes .......... 270 14.4 Cavitands ............................................. 272 14.5 Capsules .............................................. 277 14.5.1 Dimeric Capsules ............................... 277 14.5.2 Hexameric Capsules ............................. 285 14.6 Inclusion Complexes of Resorcinarenes ................. 287 14.7 The Role of Resorcinarenes in Biological Processes .... 288 14.8 Applications of Resorcinarenes ........................ 294 References .................................................... 295 Conclusions ................................................... 299 Abbreviations ................................................. 301 Index ......................................................... 305