Preface ........................................................ ix
Introduction ................................................... xi
Recent Review Articles and Monographs ........................... 1
1 - Adamanty 1-di-tert-butylphosphine ........................... 5
Benzylchlorobis(triphenylphosphine)palladium(II) ................ 7
[1,1'-Biphenyl]-2-yldicyclohexylphosphine ....................... 8
Bis(acetonitrile)[(1,2,5,6-η)-1,5-cyclooctadiene]- rhodium
(1+),tetrafluoroborate(1-) ..................................... 12
Bis(acetonitrile)dichloropalladium(II) ......................... 15
Bis(allyl)di-μ-chlorodipalladium ............................... 31
(R,R)-1,2-Bis(aminocarbonylphenyl-2'-
diphenylphosphino)cyclohexane .................................. 54
Bis(benzonitrile)dibromopalladium(II) .......................... 59
Bis(benzonitrile)dichloropalladium(II) ......................... 60
Bis(bicyclo[2.2.1]hepta-2,5-diene)dichlorodirhodium ............ 84
Bis[(lR)-[1,1'-binaphthalene]-2,2'-diylbis[diphenyl-
phosphine-kP]]di-μ-hydroxydirhodium ............................ 88
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) .............. 90
[[2,6-Bis[[(bis(l-methylethyl)phosphino-P]methyl]-3,5
dimethylphenyl]methyl-C]trifluoroacetato-0)palladium ........... 91
Bis[( 1,2,5,6-η)-1,5-cyclooctadiene]di-μ-hydroxydirhodium ...... 92
Bis[( 1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydirhodium ...... 94
Bis(1,5-cyclooctadiene)nickel(0) ............................... 95
Bis[(l,2,5,6-η)-l,5-cyclooctadiene]rhodium(1+),
Hexafluoroantimonate(1-) ...................................... 114
Bis(dibenzylideneacetone)palladium(0) ......................... 118
l,3-Bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-
2-ylidene ..................................................... 124
l,3-Bis(2,6-diisopropylphenyl)-imidazol-2-ylidene ............. 126
Bis(1,1-dimethylethyl)[2',4',6'-tris (1-methylethyl)
[1,1'-biphenyl]-2-yl]phosphine and Dicyclohexyl
[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]
phosphine ..................................................... 127
(R)- & (S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl ........ 130
1,4-Bis(diphenylphosphino)butane .............................. 141
(2R,3R)-2,3-Bis(diphenylphosphino)butane ...................... 142
l,2-Bis(diphenylphosphino)ethane .............................. 144
1,l'-Bis(diphenylphosphino)ferrocene .......................... 146
Bis[2-(diphenylphosphino)phenyl]ether (DPE-phos) .............. 155
1,3-Bis(diphenylphosphino)propane ............................. 161
Bis(η2-ethene)(2,4-pentanedionato-(O,0')rhodium ............... 163
Bis(triphenylphosphine)[1,2-bis(diphenylphosphino)-
ethane]palladium(0) ........................................... 165
Bis(tripheny lphosphine)nickel(O) ............................. 167
Bis(triphenylphosphine)palladium(II) acetate .................. 168
Bis[tri(o-tolyl)phosphine]palladium ........................... 173
Bromo(o-tolyl)bis(triethylphosphine)nickel(II) ................ 182
1-Butyl-3-methylimidazolium Hexafluorophosphate
([Bmim]PF6) ................................................... 182
(R,S>CAMPHOS .................................................. 189
Carbonyl(chloro)bis(triphenylphosphine)rhodium(I) ............. 190
Chloro(1,5-cyclooctadiene)rhodium(I) Dimer .................... 199
Chlorotris(triphenylphosphine)rhodium(I) ...................... 206
Cobalt(II) Chloride ........................................... 218
Copper ........................................................ 222
Copper(II) Acetate ............................................ 226
Copper(II) Acetylacetonate .................................... 232
Copper(I) Bromide ............................................. 235
Copper Bronze ................................................. 242
Copper(II) Chloride ........................................... 243
Copper(I) Chloride-Oxygen ..................................... 250
Copper(II) Hydroxide .......................................... 264
Copper(I) Iodide .............................................. 264
Copper(I) Iodide-Potassium Naphthalenide ...................... 275
Copper(I) Iodide-Triethyl Phosphite ........................... 275
Copper(I) Oxide ............................................... 276
Copper(I) Trifluoromethanesulfonate ........................... 281
[(1R,2R,3S,4S)-1,2,3,4-Cyclopentanetetrakis(methylene)]-
tetrakis[diphenyl]phosphine ................................... 303
Diacetatobis(tri-o-tolylphosphine)palladium(II) ............... 307
Dibromobis(triphenylphosphine)nickel(II) ...................... 307
Dibromobis(triphenylphosphine)palladium(II) ................... 309
2-(Di-tert-butylphosphino)biphenyl ............................ 310
Dicarbonyl(acetylacetonato) rhodium(I) ........................ 314
Dichloro[ 1,4-bis(diphenylphosphino)butane]nickel(II) ......... 316
Dichloro[ 1,4-bis(diphenylphosphino)butane]palladium(II) ...... 318
Dichlorof 1,2-bis(diphenylphosphino)ethane]palladium(II) ...... 320
Dichloro[ 1,1'-bis(diphenylphosphino)ferrocene]-
palladium(II) ................................................. 321
Dichlorobis(tricyclohexylphosphine)palladium .................. 322
Dichlorobis(triphenylphosphine)nickel(II) ..................... 326
Dichlorobis(triphenylphosphine)palladium(II) .................. 332
Dichlorobis(tri-o-tolylphosphine)palladium(II) ................ 343
Dichloro[2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis-
(diphenylphosphino)butane]palladium(II) ....................... 345
Dicyclohexyl(2',6'-dimethoxy [1,1'-biphenyl]-2-yl)-
phosphine (S-Phos) ............................................ 346
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)-biphenyl ....... 348
(R)-1-[(1R)-1 -(Dicyclohexylphosphino)ethyl]-2-
(diphenylphosphino)-ferrocene, (2S)-1 -[(IR)-1-
(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)-
ferrocene, (Josiphos) ......................................... 353
2-(2'-Dicyclohexylphosphinophenyl)-2-methyl-1,3-dioxolane ..... 364
1-(4,5-Dihydro-4-phenyl-2-oxazolyl)-2-(diphenyl-phosphino)
ferrocene ..................................................... 365
(1,3-Diisopropylimidazol-2-ylidene)(3-chloropyridyl)
palladium(II)chloride (PEPPSI) ................................ 367
Dilithium Tetrachlorocuprate(II) .............................. 370
Dilithium Tetrachloropalladate(II) ............................ 375
(R)-N[2-(N,N-Dimethylamino)ethyl]-N-methyl-1-[(S)-1',
2-bis(diphenylphosphino)ferrocenyl]ethylamine ................. 377
(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]-
ethylamine .................................................... 380
(4S)4-(1,1-Dimethylethyl)-2-1-[(11bS)dinaphtho-
[2,1-d:l',2'f][1,3,2]-dioxaphosphepin-4-yloxy]-1 -
methylethyl-4,5-dihydrooxazole ................................ 381
(1R,2S,4R,5S)-2,5-Dimethyl-7-phenyl-7-phosphabi-
cyclo[2.2.1]heptane ........................................... 384
(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[diphenyl-phosphine
(Xantphos) .................................................... 385
2'-(Diphenylphosphino)-N,N-dimethyl[1,1'-binaphthalen]-
2-amine ....................................................... 387
(S)-2-[2-(Diphenylphosphino)phenyl]-4-phenyloxazoline ......... 391
Encapsulated Palladium Catalysts .............................. 403
Hydrotetrakis(triphenylphosphine)rhodium ...................... 409
Iodo(phenyl)bis(triphenylphosphine)palladium(II) .............. 413
Iron(III) Chloride ............................................ 414
Lithium Trichloropalladate .................................... 423
(Maleic anhydride)bis(triphenylphosphine)palladium ............ 425
Merrifield-diphenylphosphine Palladium Complexes .............. 430
Nickel ........................................................ 435
Nickel(II) Acetylacetonate .................................... 436
Nickel(II) Bromide ............................................ 442
Nickel-in-Charcoal (NiII/C) .................................... 444
Nickel(II) Chloride ........................................... 447
(R,R)-(-)-NORPHOS, (S,S)-(+)-NORPHOS .......................... 451
Palladium(II) Acetate ......................................... 459
Palladium(II) Acetylacetonate ................................. 483
Palladium(II) Chloride ........................................ 484
Palladium(II) Chloride-Silver(I) Acetate ...................... 502
Palladium-Graphite ............................................ 502
Palladium Nanoparticles ....................................... 503
Palladium(II) Trifluoroacetate ................................ 515
1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene
(Q-Phos) ...................................................... 516
Potassium Tetrachloropalladate(II) ............................ 519
Proazaphosphatranes ........................................... 523
Silver(I) Oxide ............................................... 527
Tetrakis(acetonitrile)copper(I) Perchlorate ................... 533
Tetrakis(acetonitrile)copper(I) Tetrafluoroborate ............. 537
Tetrakis(acetonitrile)palladium Tetrafluoroborate ............. 542
Tetrakis(triisopropyl phosphite)palladium(O) .................. 547
Tetrakis(triphenylphosphine)nickel(0) ......................... 548
Terrakis(triphenylphosphine)palladium(0) ...................... 550
Tri-tert-butylphosphine ....................................... 559
Tri-fert-butylphosphine Tetrafluoroborate ..................... 562
Tricyclohexylphosphine ........................................ 566
Tri-2-furylphosphine (TFP) .................................... 569
Trimethyl Phosphite ........................................... 576
Triphenylarsine ............................................... 582
Triphenyl Phosphite ........................................... 587
Tris(acetoacetonyl)cobalt ..................................... 593
Tris(acetonitrile)tricarbonyltungsten ......................... 595
Tris(acetylacetonato)iron(III) ................................ 596
Tris(dibenzoylmethide)iron(III) ............................... 600
Tris(dibenzylideneacetone)dipalladium-Chloroform .............. 602
Tris(triphenylphosphine)nickel(0) ............................. 607
m-Trisulfonated Triphenylphosphine ............................ 609
Tri-o-Tolylphosphine .......................................... 620
Zinc/Nickel Couple ............................................ 625
List of Contributors .......................................... 627
Reagent Formula Index ......................................... 639
Subject Index ................................................. 643
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