 | Ferraro J.R. Introductory Raman spectroscopy / J.R.Ferraro, K.Nakamoto, C.W.Brown. - San Diego; London: Academic Press, 2003. - xiii, 434 p.: ill. - Incl. bibl. ref. - Ind.: p.423-434. - ISBN 0-12-254105-7; ISBN 978-0-12-254105-6
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Preface to the Second Edition ................................... x
Acknowledgments ................................................ xi
Preface to the First Edition .................................. xii
Acknowledgments .............................................. xiii
Chapter 1. Basic Theory ......................................... 1
1.1 Historical Background of Raman Spectroscopy ............. 1
1.2 Energy Units and Molecular Spectra ...................... 2
1.3 Vibration of a Diatomic Molecule ........................ 7
1.4 Origin of Raman Spectra ................................ 13
1.5 Factors Determining Vibrational Frequencies ............ 18
1.6 Vibrations of Polyatomic Molecules ..................... 19
1.7 Selection Rules for Infrared and Raman Spectra ......... 22
1.8 Raman versus Infrared Spectroscopy ..................... 26
1.9 Depolarization Ratios .................................. 27
1.10 The Concept of Symmetry ................................ 30
1.11 Point Symmetry Elements ................................ 31
1.12 The Character Table .................................... 43
1.13 Classification of Normal Vibrations by Symmetry ........ 48
1.14 Symmetry Selection Rules ............................... 52
1.15 Resonance Raman Spectra ................................ 54
1.16 Space Group Symmetry ................................... 61
1.17 Normal Vibrations in a Crystal ......................... 67
1.18 Selection Rules for Solids (Factor Group) .............. 70
1.19 Polarized Raman Spectra of Single Crystals ............. 78
1.20 Normal Coordinate Analysis ............................. 79
1.21 Band Assignments and Isotope Shifts .................... 86
References .................................................. 89
General References .......................................... 91
Chapter 2. Instrumentation and Experimental Techniques ......... 95
2.1 Major Components ....................................... 95
2.2 Excitation Sources ..................................... 96
2.3 Sample Illumination ................................... 103
2.4 Wavelength Selectors .................................. 105
2.5 Detection ............................................. 112
2.6 Instrument Calibration ................................ 117
2.7 Sampling Techniques ................................... 123
2.8 Fluorescence Problems ................................. 137
2.9 Raman Difference Spectroscopy ......................... 138
2.10 Miniature Raman Spectrometers ......................... 140
References ................................................. 143
General References ......................................... 146
Chapter 3. Special Techniques ................................. 147
3.1 High-Pressure Raman Spectroscopy ...................... 147
3.2 Raman Microscopy ...................................... 154
3.3 Surface-Enhanced Raman Spectroscopy (SERS) ............ 161
3.4 Raman Spectroelectrochemistry ......................... 168
3.5 Time-Resolved Raman (TR2) Spectroscopy ................ 174
3.6 Matrix-Isolation Raman Spectroscopy ................... 179
3.7 2D Correlation Raman Spectroscopy ..................... 184
3.8 Raman Imaging Spectrometry ............................ 188
3.9 Nonlinear Raman Spectroscopy .......................... 194
References ................................................. 202
Chapter 4. Materials Applications ............................. 207
4.1 Applications to Structural Chemistry .................. 207
4.2 Solid State Applications .............................. 237
References ................................................. 263
Chapter 5. Analytical Chemistry ............................... 267
5.1 Preprocessing Spectra ................................. 267
5.2 Full-Spectra Processing Methods ....................... 277
5.3 Quantitative Analysis ................................. 283
5.4 Spectral Searches ..................................... 285
5.5 Discriminant Analysis ................................. 288
References ................................................. 292
Chapter 6. Biochemical and Medical Applications ............... 295
6.1 Biochemical Applications .............................. 296
6.2 Medical Applications .................................. 313
References ................................................. 322
Chapter 7. Industrial, Environmental and Other Applications ... 325
7.1 Industrial Applications ............................... 325
7.2 Environmental Applications ............................ 342
7.3 Other Applications .................................... 350
References ................................................. 361
Appendices .................................................... 363
Index ......................................................... 423
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