Agrawal J.P. High energy materials: propellants, explosives and pyrotechnics (Weinheim, 2010). - ОГЛАВЛЕНИЕ / CONTENTS
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ОбложкаAgrawal J.P. High energy materials: propellants, explosives and pyrotechnics. - Weinheim: Wiley-VCH, 2010. - xxxiv, 464 p.: ill. - Incl. bibl. ref. - Ind.: p.449-464. - ISBN 978-3-527-32610-5
 

Оглавление / Contents
 
Preface ....................................................... XIX
Acknowledgments ............................................... XXI
Abbreviations ............................................... XXIII

1. Salient Features of Explosives ............................... 1
   1.1.  Introduction ........................................... 1
   1.2.  Definition ............................................. 2
         1.2.1.  Evolution of Heat .............................. 3
         1.2.2.  Rapidity of Reaction ........................... 3
   1.3.  Classification ......................................... 4
         1.3.1.  Military Explosives ............................ 6
                 1.3.1.1.  Detonating or High Explosives ........ 6
                 1.3.1.2.  Deflagrating or Low Explosives ....... 7
                 1.3.1.3.  Pyrotechnics ......................... 9
         1.3.2.  Civil Explosives ............................... 9
                 1.3.2.1.  Permitted or Permissible
                           Explosives ........................... 9
                 1.3.2.2.  Non-permitted Explosives ............ 11
   1.4.  Fundamental Features .................................. 14
         1.4.1.  Compatibility and Stability ................... 14
         1.4.2.  Oxygen Balance (OB) ........................... 17
         1.4.3.  Sensitivity and Sensitiveness ................. 19
                 1.4.3.1.  Sensitivity to Impact ............... 20
                 1.4.3.2.  Sensitivity to Friction ............. 20
                 1.4.3.3.  Sensitivity to Shock ................ 20
                 1.4.3.4.  Sensitivity to Spark ................ 20
                 1.4.3.5.  Sensitivity to Heat ................. 20
         1.4.4.  Heat of Formation ............................. 24
         1.4.5.  Heat of Explosion and Gaseous Products ........ 27
         1.4.6.  Velocity of Detonation (VOD) .................. 30
         1.4.7.  Detonation Pressure (DP or Pcj) ............... 31
         1.4.8.  Explosive Power or Strength ................... 32
         1.4.9.  Brisance ...................................... 32
   1.5.  Additional Requirements for Military Explosives ....... 33
         1.5.1.  Volatility .................................... 34
         1.5.2.  Toxicity ...................................... 34
         1.5.3.  Hygroscopicity ................................ 34
         1.5.4.  Density ....................................... 35
         1.5.5.  Life .......................................... 35
         1.5.6.  Availability, Cost and Demilitarization
                 or Recycling .................................. 35
         1.5.7.  Eco-friendliness .............................. 36
   1.6.  Applications of Explosives ............................ 37
         1.6.1.  Military Applications ......................... 38
                 1.6.1.1.  Shells .............................. 39
                 1.6.1.2.  Bombs ............................... 40
                 1.6.1.3.  Grenades ............................ 40
                 1.6.1.4.  Torpedoes ........................... 40
                 1.6.1.5.  Shaped Charges ...................... 41
                 1.6.1.6.  Warheads ............................ 41
         1.6.2.  Commercial Applications ....................... 43
                 1.6.2.1.  Coal Mining ......................... 43
                 1.6.2.2.  Tunneling ........................... 44
                 1.6.2.3.  Quarrying ........................... 44
                 1.6.2.4.  Other Mining ........................ 45
         1.6.3.  Military Explosives and Devices for
                 Commercial Applications ....................... 45
                 1.6.3.1.  Detonators .......................... 45
                 1.6.3.2. Pilot Seat Ejection System ........... 45
                 1.6.3.3.  High Altitude Fuel .................. 46
                 1.6.3.4.  Air Re-generating Composition ....... 46
                 1.6.3.5.  Metal Cladding and Welding .......... 47
                 1.6.3.6.  Metal Working ....................... 48
                 1.6.3.7.  Explosive Forming ................... 48
                 1.6.3.8.  Explosive Cutting ................... 49
         1.6.4.  Space Applications ............................ 49
                 1.6.4.1.  Solid and Liquid Rockets for Space
                           Applications ........................ 49
                 1.6.4.2.  Various Indian Satellite Launch
                           Vehicles ............................ 51
                 1.6.4.3.  Explosives, Propellants (Oxidizers,
                           Binders and Plasticizers) and
                           Pyrotechnics for Satellite Launch
                           Vehicles ............................ 52
         1.6.5.  Nuclear Applications .......................... 54
                 1.6.5.1.  Types of Nuclear Weapons ............ 54
                 1.6.5.2.  Assembly ............................ 55
                 1.6.5.3.  Fissile Materials and Explosive
                           Lenses .............................. 56
                 1.6.5.4.  Explosives and Binders for Nuclear
                           Weapons ............................. 58
         1.6.6.  Miscellaneous Applications .................... 58
                 1.6.6.1.  Agriculture ......................... 58
                 1.6.6.2.  Medical Industry .................... 61
                 1.6.6.3.  Food Industry ....................... 61
                 1.6.6.4.  Civil Engineering ................... 62
                 1.6.6.5.  Automobile Industry ................. 62
                 1.6.6.6.  Oil and Gas Industry ................ 62
   References .................................................. 63

2. Status of Explosives ........................................ 69
   2.1.  Historical Aspects .................................... 69
   2.2.  Status of Current and Future Explosives ............... 70
         2.2.1.  Black Powder .................................. 71
         2.2.2.  Trinitrotoluene ............................... 71
         2.2.3.  Tetryl ........................................ 72
         2.2.4.  Nitroglycerine ................................ 72
         2.2.5.  Dynamite ...................................... 73
         2.2.6.  Pentaerythritol Tetranitrate .................. 73
         2.2.7.  Nitrocellulose ................................ 74
         2.2.8.  Polyvinyl Nitrate ............................. 75
         2.2.9.  Mercury Fulminate ............................. 76
         2.2.10. Lead Azide .................................... 76
         2.2.11. Picric Acid, Lead Picrate and
                 Ammonium Picrate .............................. 78
         2.2.12. Lead Styphnate (Lead-2,4,6-
                 trinitroresorcinate) .......................... 79
         2.2.13. Diazodinitropheno ............................. 79
         2.2.14. Tetrazene ..................................... 80
         2.2.15. Mercuric-5-nitrotetrazole ..................... 81
         2.2.16. Research Department Explosive ................. 81
         2.2.17. High Melting Explosive (or Her Majesty's
                 Explosive) .................................... 82
         2.2.18. 'Heat-Resistant' or 'Thermally Stable'
                 Explosives .................................... 83
                 2.2.18.1. General Approaches for the
                           Synthesis of TATB, HNS,PATO etc. .... 84
                           Salt Formation ...................... 84
                           Introduction of Amino Groups ........ 84
                           Introduction of Conjugation ......... 89
                           Condensation with Triazole Ring/s ... 91
                 2.2.18.2. 3,3'-Diamino-2,2',4,4',6,6'-
                           exanitrodiphenyl .................... 93
                 2.2.18.3. N2,N4,N6-Tripicrylmelamine or
                           2,4,6-Tris(picrylamino)-l,3,5-
                           triazine Series of Explosives ....... 93
                 2.2.18.4. Tetranitrodibenzo-l,3a,4,4a-
                           tetraazapentalene ................... 95
                 2.2.18.5. 2,6-Bis(picrylamino)-3,5-
                           dinitropyridine ..................... 95
                 2.2.18.6. 2,5-Dipicryl-l,3,4-oxadiazole ....... 96
                 2.2.18.7. 2,2',2",4,4',4",6,6',6"-
                           Nonanitroterphenyl .................. 96
                 2.2.18.8. 3,5-Diamino-2,6-dinitropyridine-
                           N-oxide ............................. 97
                 2.2.18.9. N,N'-Bis(l,2,4-triazol-3-yl)-
                           4,4'-diamino-2,2',3,3',5,5',6,6'-
                           octanitroazobenzene 97
         2.2.19. High Performance (High Density and High
                 VOD)Explosives ............................... 99
                 2.2.19.1. General Synthetic Approaches for
                           High Performance Explosives 
                           (HNIW/CL-20 etc.) .................. 100
                           Replacement of the Nitro Group by
                           Furoxano Group ..................... 100
                           Introduction of SF5 Groups into
                           Nitro Compounds .................... 102
                           Strained and Cage Compounds ........ 103
                 2.2.19.2. 1,3,4,6-Tetranitroglycoluril ....... 106
                 2.2.19.3. Tetranitropropanediurea ............ 106
                 2.2.19.4. 1,3,5,5-Tetranitrohexahydropyri-
                           midine ............................. 107
         2.2.20. Melt-Castable Explosives ..................... 108
                 2.2.20.1. Tris-X and Methyl Tris-X ........... 108
                 2.2.20.2. 1,3,3-Trinitroazetidine ............ 109
                 2.2.20.3. 4,4'-Dinitro-3,3'-bifurazan ........ 110
         2.2.21. Insensitive High Explosives .................. 110
                 2.2.21.1. Oxynitrotriazole or
                           Nitrotriazolone .................... 112
                 2.2.21.2. Dinitroglycoluril .................. 113
                 2.2.21.3. Aminonitrotriazole ................. 114
                 2.2.21.4. Trans-l,4,5,8-tetranitro-l,4,5,8-
                           tetraazadecalin .................... 114
         2.2.22. Energetic Binders and Plasticizers ........... 115
                 2.2.22.1. Energetic Binders .................. 115
                 2.2.22.2. Energetic Plasticizers ............. 117
         2.2.23. Energetic Materials Synthesized Using
                 Dinitrogen Pentoxide ........................... 1
         2.2.24. Newly Reported Explosives .................... 118
         2.2.25. Important Formulations Based on TATB, CL-20
                 and NTO ...................................... 120
                 2.2.25.1. TATB-based Formulations ............ 120
                 2.2.25.2. CL-20-based Formulations ........... 122
                 2.2.25.3. NTO-based Formulations ............. 124
         2.2.26. Insensitive Munitions and Some New
                 Insensitive Explosives/Formulations .......... 125
                 2.2.26.1. ROWANEX Class of PBXs .............. 126
                 2.2.26.2. SNPE's PBXs ........................ 127
                 2.2.26.3. FOI's Explosives ................... 129
                           FOX-7 .............................. 129
                           FOX-12 ............................. 130
                 2.2.26.4. American Formulations .............. 130
         2.2.27. Basic Lead Azide ............................. 131
         2.2.28. Hexakis(azidomethyl) Benzene ................. 134
         2.2.29. Tetraamine-cis-bis(5-nitro-2H-Tetrazolato-
                 N2) Cobalt (III) Perchlorate ................. 134
         2.2.30. Octanitrocubane .............................. 137
         2.2.31. Nickel Hydrazine Nitrate ..................... 139
         2.2.32. Furazan-, Furoxan- and Tetrazine-Based
                 Explosives ................................... 140
         2.2.33. High Nitrogen Content-High Energy
                 Materials .................................... 141
         2.2.34. Fuel-Air Explosives .......................... 144
   2.3.  Future Scope for Research ............................ 147
         2.3.1.  High Performance, Thermally Stable and
                 Insensitive Explosives
         2.3.2.  Melt-Castable Explosives ..................... 148
         2.3.3.  Energetic Binders and Plasticizers ........... 148
         2.3.4.  Particle Size of Explosives .................. 148
         2.3.5.  Eco-Friendly Production Processes and
                 Explosives 149
   References ................................................. 150

3. Processing and Assessment Techniques for Explosives ........ 163
   3.1.  Processing Techniques for Explosives ................. 163
         3.1.1.  Casting ...................................... 164
                 3.1.1.1.  Melt-casting ....................... 164
                 3.1.1.2.  Normal Casting ..................... 165
                 3.1.1.3.  Vibration or Sedimentation
                           Casting ............................ 166
                 3.1.1.4.  Squeeze or Pressure Casting ........ 166
         3.1.2.  Extrusion .................................... 166
         3.1.3.  Pressing ..................................... 166
                 3.1.3.1.  Unidirectional Pressing ............ 167
                 3.1.3.2.  Double Action Pressing ............. 167
                 3.1.3.3.  Incremental Pressing ............... 167
                 3.1.3.4.  Hydrostatic Pressing ............... 168
                 3.1.3.5.  Isostatic Pressing ................. 168
   3.2.  Formulation Fundamentals ............................. 170
         3.2.1.  Current Formulations ......................... 170
         3.2.2.  Aluminized Explosive Formulations ............ 171
         3.2.3.  Sheet Explosives ............................. 171
         3.2.4.  Plastic Bonded Explosives .................... 173
   3.3.  Assessment of Explosives ............................. 175
         3.3.1.  Determination of Compatibility and
                 Stability of Explosives ...................... 176
                 3.3.1.1.  Vacuum Stability Test .............. 177
                 3.3.1.2.  Heat Test .......................... 179
                 3.3.1.3.  Impact Sensitivity Test ............ 179
         3.3.2.  Sensitivity of Explosives to Heat, Impact,
                 Friction, Spark and Shock .................... 180
                 3.3.2.1.  Determination of Heat
                           Sensitivity ........................ 180
                           Explosion Delay .................... 180
                           Explosion Temperature .............. 181
                           Activation Energy .................. 182
                           Thermal Analysis ................... 183
                 3.3.2.2.  Determination of Impact
                           Sensitivity ........................ 188
                 3.3.2.3.  Determination of Friction
                           Sensitivity ........................ 195
                 3.3.2.4.  Determination of Electric Spark
                           Sensitivity ........................ 197
                 3.3.2.5.  Determination of Shock
                           Sensitivity ........................ 197
         3.3.3.  Determination of Detonation Velocity ......... 198
                 3.3.3.1.  Pin Oscillographic Technique ....... 198
                 3.3.3.2. Dautriche Method .................... 202
         3.3.4.  Determination of Detonation Pressure ......... 203
         3.3.5.  Determination of Strength .................... 204
   References ................................................. 205

4. Propellents ................................................ 209
   4.1   Classification of Propellants ........................ 209
   4.2.  Liquid Propellants ................................... 209
   4.3.  Solid Propellants .................................... 213
         4.3.1.  Homogeneous Propellants ...................... 213
                 4.3.1.1.  Single-Base Propellants ............ 213
                 4.3.1.2.  Double-Base Propellants ............ 214
                 4.3.1.3.  Triple-Base Propellants ............ 214
         4.3.2.  Heterogeneous Propellants .................... 214
                 4.3.2.1.  Composite Propellants .............. 214
                 4.3.2.2.  Composite Modified Double-Base
                           Propellants ........................ 215
                 4.3.2.3.  Fuel-Rich Propellants .............. 215
   4.4.  Hybrid Propellants ................................... 217
   4.5.  Thixotropic Propellants .............................. 217
   4.6.  Performance of Propellants ........................... 218
         4.6.1.  Gun Propellants .............................. 218
                 4.6.1.1.  Force Constant ..................... 218
                 4.6.1.2.  Burning Rate Coefficients .......... 219
                 4.6.1.3.  Vivacity ........................... 219
                 4.6.1.4.  Muzzle Velocity .................... 219
                 4.6.1.5.  Efficiencies of Gun System and
                           Charge ............................. 220
         4.6.2.  Rocket Propellants ........................... 220
                 4.6.2.1.  Burn Rate .......................... 221
                 4.6.2.2.  Thrust ............................. 222
                 4.6.2.3.  Specific Impulse (lsp) ............. 222
                 4.6.2.4.  Chamber Pressure ................... 223
                 4.6.2.5.  Characteristic Velocity (C*) ....... 223
                 4.6.2.6.  Temperature Sensitivity ............ 224
   4.7.  Formulation of Gun Propellants ....................... 226
   4.8.  Ingredients of Gun Propellants ....................... 227
         4.8.1.  High Energy Propellants ...................... 228
         4.8.2.  Low Vulnerability Gun Propellants ............ 228
                 4.8.2.1.  Ingredients of LOVA Gun
                           Propellants ........................ 229
         4.8.3.  Liquid Gun Propellants ....................... 231
                 4.8.3.1.  Hydroxyl Ammonium Nitrate Liquid
                           Gun Propellants
                 4.8.3.2.  DMAZ Liquid Gun Propellants ........ 233
   4.9.  Ingredients of Solid Rocket Propellants .............. 234
         4.9.1.  Oxidizers .................................... 234
                 4.9.1.1.  Ammonium Nitrate ................... 235
                 4.9.1.2.  Ammonium Dinitramide ............... 237
                 4.9.1.3.  Hydrazinium Nitroformate ........... 239
         4.9.2.  Binders ...................................... 243
                 4.9.2.1.  Characteristics of Binders ......... 243
                 4.9.2.2.  Polyurethanes as Binders ........... 244
                 4.9.2.3.  Novel Binders ...................... 249
                           Inert or Non-Energetic Binders ..... 249
                           Energetic Binders .................. 252
         4.9.3.  Metal Fuels .................................. 265
         4.9.4.  Plasticizers ................................. 267
                 4.9.4.1.  Classification of Plasticizers ..... 267
                 4.9.4.2.  Characteristics of Plasticizers .... 268
                 4.9.4.3.  Functions of Plasticizers .......... 268
                 4.9.4.4.  Migration of Plasticizers .......... 268
                 4.9.4.5.  Novel Plasticizers ................. 271
                           Nitroxyethyl Nitramine
                           Plasticizers ....................... 271
                           Polynitro Aliphatic Plasticizers ... 272
                           Rowanite 8001 or K-10
                           Plasticizer ........................ 273
                           Azido Plasticizers ................. 273
                           Energetic Oligomeric
                           Plasticizers ....................... 274
                           Nitrate Ester Plasticizers ......... 275
         4.9.5.  Bonding Agents ............................... 275
         4.9.6.  Stabilizers .................................. 277
         4.9.7.  Burn-Rate Modifiers .......................... 280
                 4.9.7.1.  Burn-Rate Modifiers for DB
                           Propellants ........................ 281
                 4.9.7.2.  Less Toxic and Non-Toxic Burn-
                           Rate Modifiers for DB
                           Propellants ........................ 284
                 4.9.7.3.  Burn-Rate Modifiers for CMDB
                           Propellants ........................ 284
                 4.9.7.4.  Burn-Rate Modifiers for Composite
                           Propellants ........................ 284
                           Metallic Oxides .................... 284
                           Ferrocene Derivatives .............. 287
                           Butacene ........................... 287
   4.10. Inhibition of Rocket Propellants ..................... 289
         4.10.1. Characteristics of Inhibitors ................ 291
         4.10.2. Testing of Inhibitors ........................ 291
         4.10.3. Ballistic Evaluation of Inhibited
                 Propellants .................................. 292
         4.10.4. Materials for Inhibition ..................... 293
         4.10.5. Techniques of Inhibition ..................... 294
                 4.10.5.1. Sleeve Technique ................... 294
                 4.10.5.2. Tape-Winding Technique ............. 294
                 4.10.5.3. Casting Technique .................. 295
                 4.10.5.4. Thread-Winding Technique ........... 295
                 4.10.5.5. Inhibitor Sleeve Technique ......... 296
         4.10.6. Inhibition of Double-Base Propellants ........ 298
                 4.10.6.1. Tailoring of Properties of
                           Unsaturated Polyesters ............. 300
                 4.10.6.2. Recent Trends ...................... 301
         4.10.7. Inhibition of Composite Propellants .......... 302
                 4.10.7.1. Chemistry of Epoxy Resins .......... 302
                           Epoxy Resins ....................... 304
                           Novolac Epoxy Resins ............... 304
                           Synthesis .......................... 305
                           Curing Agents for Epoxy Resins ..... 306
                           Cure Mechanism ..................... 308
                 4.10.7.2. Novel Systems ...................... 308
                 4.10.7.3. Plasticizer Migration in
                           Composite Propellants .............. 308
         4.10.8. Inhibition of CMDB Propellants ............... 308
   4.11. Insulation of Rocket Motors .......................... 313
         4.11.1. Characteristics of Insulators or Insulating
                 Materials .................................... 313
         4.11.2. Materials for Insulation ..................... 314
         4.11.3. Process for Insulation of Motors ............. 315
         4.11.4. Future Materials for Insulation .............. 325
   References ................................................. 316

5. Pyrotechnics ............................................... 331
   5.1.  Introduction ......................................... 331
   5.2.  General Features of Pyrotechnics ..................... 332
   5.3.  Ingredients of Pyrotechnic Formulations .............. 333
         5.3.1.  Fuels ........................................ 333
         5.3.2.  Oxidizers .................................... 334
         5.3.3.  Binders ...................................... 334
         5.3.4.  Coolants ..................................... 335
         5.3.5.  Retardants ................................... 335
         5.3.6.  Dyes ......................................... 335
         5.3.7.  Color Intensifies ............................ 335
         5.3.8.  Moderators ................................... 335
   5.4.  Important Characteristics of Ingredients for
         Pyrotechnic Formulations ............................. 336
         5.4.1.  Density ...................................... 336
         5.4.2.  Hygroscopicity ............................... 337
         5.4.3.  Melting and Boiling Points and
                 Decomposition Temperatures ................... 338
         5.4.4.  Oxygen Content of Oxidizers .................. 339
         5.4.5.  Thermal Conductivity of Fuels and
                 Containers ................................... 339
         5.4.6.  Nature of Combustion Products ................ 339
         5.4.7.  Toxicity of Ingredients ...................... 340
   5.5.  Types of Pyrotechnic Formulations .................... 341
         5.5.1.  Illuminating Formulations .................... 341
                 5.5.1.1.  Chemical Nature of Fuel and
                           Oxidizer, Their Proportions
                           and Particle Size .................. 342
                 5.5.1.2.  Formulations of Tracers ............ 346
                 5.5.1.3.  Photon 1 ash Formulations .......... 347
                 5.5.1.4.  Signal Formulations ................ 347
                 5.5.1.5.  Infrared Flare Formulations ........ 348
                 5.5.1.6.  Some Resins for Illuminating
                           Formulations ....................... 351
                           Liquid Polysulfides ................ 351
                           Epoxy-Liquid Polysulfide Blends .... 352
                           Vinyl Acetate Alcohol Resins ....... 352
         5.5.2.  Delay Formulations ........................... 354
                 5.5.2.1.  Requirements of an Ideal Delay
                           Formulation ........................ 355
                 5.5.2.2.  Factors Affecting the Performance
                           of Delay Formulations .............. 355
                 5.5.2.3.  Types of Delay Formulations ........ 356
                           Gas-producing (Slagless) Delay
                           Formulations ....................... 356
                           Gasless Delay Formulations ......... 357
         5.5.3.  Smoke Formulations ........................... 358
                 5.5.3.1.  Requirements for Smokes ............ 359
                 5.5.3.2.  Classification of Smokes ........... 359
                 5.5.3.3.  Types of Smoke Agents .............. 360
                 5.5.3.4.  Colored Smokes ..................... 362
                 5.5.3.5.  Lachrymatory Smokes ................ 364
                 5.5.3.6.  Non-toxic and Eco-friendly
                           Smokes ............................. 364
                 5.5.3.7.  Infrared Screening Smokes .......... 365
                 5.5.3.8.  Chemistry of Phosphorus ............ 367
                           Stability of Red Phosphorus ........ 369
                           Applications for Red Phosphorus .... 370
         5.5.4.  Incendiary Formulations ...................... 373
                 5.5.4.1.  Characteristics of Incendiary
                           Materials .......................... 374
                           Essential Characteristics .......... 374
                           Desirable Characteristics .......... 374
                 5.5.4.2.  Liquid Incendiaries ................ 375
                 5.5.4.3.  Solid Incendiaries ................. 376
                 5.5.4.4.  Chemistry of Napalm ................ 379
   5.6.  Performance Assessment of Pyrotechnic Formulations ... 381
         5.6.1.  Ignition Temperature ......................... 381
         5.6.2.  Mechanical Properties ........................ 381
         5.6.3.  Moisture Absorption .......................... 381
         5.6.4.  Heat Output and Gas Volume ................... 382
         5.6.5.  Luminous Intensity ........................... 382
         5.6.6.  IR Intensity ................................. 383
         5.6.7.  Burning Rate ................................. 384
         5.6.8.  Screening Performance of Smokes .............. 385
                 5.6.8.1.  Total Obscuring Power .............. 385
                 5.6.8.2.  Yield Factor (Y) ................... 386
                 5.6.8.3.  Mass Extinction Coefficient (a) .... 386
                 5.6.8.4.  Obscuration Effectiveness .......... 387
   5.7.  Life of Ammunition with Pyrotechnic Devices .......... 387
   5.8.  Nanomaterials: Various Aspects and Use in HEM
         Formulations ......................................... 389
         5.8.1.  Synthesis of Nanomaterials ................... 390
                 5.8.1.1.  Physical Methods ................... 390
                 5.8.1.2.  Chemical Methods ................... 391
         5.8.2.  Carbon Nanotubes ............................. 393
                 5.8.2.1.  Synthesis of CNTs .................. 393
                 5.8.2.2.  Some Properties and Applications
                           of CNTs ............................ 394
         5.8.3.  Nanosized Fuels .............................. 394
                 5.8.3.1.  Nano-Aluminum Powder ............... 394
                 5.8.3.2.  Other Nanometal Powders ............ 396
         5.8.4.  Nano-oxidizers ............................... 397
         5.8.5.  General Properties of Nanomaterials .......... 398
         5.8.6.  Nanomaterials for Pyrotechnic Formulations ... 398
         5.8.7.  Nanomaterials for Propellant Formulations .... 400
         5.8.8.  Nanomaterials for Explosive Formulations ..... 401
   5.9.  Recent and Future Trends in Pyrotechnics ............. 401
         5.9.1.  Energetic Binders, Plasticizers and
                 Oxidizers .................................... 401
         5.9.2.  Exotic Salts of Lithium, Rubidium and
                 Caesium and their Formulations ............... 402
         5.9.3.  Dinitramide Salts of Alkali Metals and Their
                 Formulations ................................. 403
         5.9.4.  Moisture Resistant Coatings for Metal
                 Powders ...................................... 404
         5.9.5.  New Fuels as Substitute for Charcoal ......... 405
         5.9.6.  High Nitrogen Content-High Energy Materials
                 for Pyrotechnic Formulations ................. 406
   References ................................................. 406

6. Explosive and Chemical Safety .............................. 413
   6.1.  Safety ............................................... 413
   6.2.  Explosive Safety ..................................... 414
         6.2.1.  UN Classification of Dangerous Goods
                 and Hazardous Chemicals ...................... 416
                 6.2.1.1.  Hazard Divisions ................... 417
                 6.2.1.2.  Compatibility Groups for
                           Explosives and Ammunition .......... 420
                 6.2.1.3.  Hazard Classification .............. 422
   6.3.  Fire Safety .......................................... 422
         6.3.1.  Fire Divisions ............................... 423
         6.3.2.  Classes of Fires, Fire Extinguishers and
                 Fire Fighting ................................ 424
                 6.3.2.1.  Classes of Fires 425
                 6.3.2.2.  Designations and Ratings of Fire
                           Extinguishers ...................... 425
                 6.3.2.3.  Fire-fighting Procedures ........... 425
   6.4.  Safety Aspects for Transportation of Explosives
         and Ammunition ....................................... 427
   6.5.  Safety Aspects for Storage of Explosives and
         Ammunition ........................................... 428
   6.6.  Safety Aspects for Handling of Explosives and
         Ammunition ........................................... 432
   6.7.  Static Electricity Hazards ........................... 433
   6.8.  Extremely Insensitive Detonating Substances and
         Ammunition ........................................... 435
   6.9.  Hazard and Risk Analysis ............................. 438
         6.9.1.  Hazards and Operability (HAZOP) .............. 438
         6.9.2.  Hazard Analysis (HAZAN) ...................... 439
   6.10. Chemical Safety ...................................... 439
   6.11. Prevention and Elimination of Explosions,
         Accidents and Fires .................................. 439
         6.11.1. Operations and Organization .................. 440
         6.11.2. Honor the Explosives ......................... 441
         6.11.3. Use of Personal Protective Equipment ......... 442
         6.11.4. Cleanliness and Good Housekeeping ............ 443
         6.11.5. Waste Collection and Disposal ................ 444
         6.11.6. Training ..................................... 445
   References ................................................. 446

Index ......................................................... 449


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Посещение N 2796 c 05.10.2010