Hydrothermal properties of materials: experimental data on aqueous phase equilibria and solution properties at elevated temperatures and pressures = Hydrothermal experimental data / ed. by V.M.Valyashko. - Chichester: Wiley, 2008. - xiv, 291 p.: ill. + 1 CD-ROM. - Incl. bibl. ref. - Ind.: p.289-291. - ISBN 978-0-470-09465-5  Место хранения:   019 | Институт теплофизики им. С.С.Кутателадзе CO РАН | Новосибирск | Библиотека

Оглавление / Contents

CD Table of Contents ........................................... ix Foreword ....................................................... xi Preface ...................................................... xiii Acknowledgements ............................................... xv 1 Phase Equilibria in Binary and Ternary Hydrothermal Systems ...................................................... 1 Vladimir M. Valyashko 1.1 Introduction ............................................ 1 1.2 Experimental methods for studying hydrothermal phase equilibria .............................................. 3 1.2.1 Methods of visual observation ................... 73 1.2.2 Methods of sampling ............................. 74 1.2.3 Methods of quenching ............................ 80 1.2.4 Indirect methods ................................ 82 1.3 Phase equilibria in binary systems ..................... 86 1.3.1 Main types of fluid phase behavior .............. 86 1.3.2 Classification of complete phase diagrams ....... 87 1.3.3 Graphical representation and experimental examples of binary phase diagrams ............... 91 1.4 Phase equilibria in ternary systems ................... 103 1.4.1 Graphical representation of ternary phase diagrams ....................................... 103 1.4.2 Derivation and classification of ternary phase diagrams ................................. 105 References ................................................. 119 2 pVTx Properties of Hydrothermal Systems .................... 135 Horacio R. Corti and Ilmutdin M. Abdulagatov 2.1 Basic principles and definitions ...................... 135 2.2 Experimental methods .................................. 136 2.2.1 Constant volume piezometers (CVP) .............. 136 2.2.2 Variable volume piezometers (VVP) .............. 137 2.2.3 Hydrostatic weighing technique (HWT) ........... 138 2.2.4 Vibrating tube densimeter (VTD) ................ 139 2.2.5 Synthetic fluid inclusion technique ............ 140 2.3 Theoretical treatment of pVTx data .................... 140 2.3.1 Excess volume .................................. 140 2.3.2 Models for the standard partial molar volume ... 153 2.4 pVTx data for hydrothermal systems .................... 159 2.4.1 Laboratory activities .......................... 159 2.4.2 Summary table .................................. 185 References ................................................. 186 3 High Temperature Potentiometry ............................. 195 Donald A. Palmer and Serguei N. Lvov 3.1 Introduction .......................................... 195 3.1.1 Reference electrodes ........................... 198 3.1.2 Indicator electrodes ........................... 198 3.1.3 Diffusion, thermal diffusion, thermoelectric, and streaming potentials ....................... 199 3.1.4 Reference and buffer solutions ................. 200 3.2 Experimental methods .................................. 200 3.2.1 Hydrogen-electrode concentration cell .......... 200 3.2.2 Flow-through conventional potentiometric cells .......................................... 202 3.3 Data treatment ........................................ 203 References ................................................. 205 4 Electrical Conductivity in Hydrothermal Binary and Ternary Systems ............................................ 207 Horacio R. Corti 4.1 Introduction .......................................... 207 4.2 Basic principles and definitions ...................... 207 4.3 Experimental methods .................................. 215 4.3.1 Static high temperature and pressure conductivity cells ............................. 215 4.3.2 Flow-through conductivity cell ................. 217 4.3.3 Measurement procedure .......................... 218 4.4 Data treatment ........................................ 219 4.4.1 Dissociated electrolytes ....................... 219 4.4.2 Associated electrolytes ........................ 219 4.4.3 Getting information from electrical conductivity data .............................. 221 4.5 General trends ........................................ 221 4.5.1 Specific conductivity as a function of temperature, concentration and density ......... 221 4.5.2 The limiting molar conductivity ................ 222 4.5.3 Concentration dependence of the molar conductivity and association constants ......... 223 4.5.4 Molar conductivity as a function of temperature and density ........................ 224 4.5.5 Conductivity in ternary systems ................ 224 References ................................................. 224 5 Thermal Conductivity ....................................... 227 Ilmutdin M. Abdulagatov and Marc J. Assael 5.1 Introduction .......................................... 227 5.2 Experimental techniques ............................... 228 5.2.1 Parallel-plate technique ....................... 228 5.2.2 Coaxial-cylinder technique ..................... 235 5.2.3 Transient hot-wire technique ................... 239 5.2.4 Conclusion ..................................... 241 5.3 Available experimental data ........................... 242 5.3.1 Temperature dependence ......................... 242 5.3.2 Pressure dependence ............................ 244 5.3.3 Concentration dependence ....................... 245 5.4 Discussion of experimental data ....................... 245 References ................................................. 246 6 Viscosity .................................................. 249 Ilmutdin M. Abdulagatov and Marc J. Assael 6.1 Introduction .......................................... 249 6.2 Experimental techniques ............................... 252 6.2.1 Capillary-flow technique ....................... 253 6.2.2 Oscillating-disk technique ..................... 255 6.2.3 Falling-body viscometer ........................ 257 6.2.4 Conclusion ..................................... 259 6.3 Available experimental data ........................... 260 6.3.1 Temperature dependence ......................... 261 6.3.2 Pressure dependence ............................ 261 6.3.3 Concentration dependence ....................... 264 6.4 Discussion of experimental viscosity data ............. 265 References ................................................. 267 7 Calorimetric Properties of Hydrothermal Solutions .......... 271 Vladimir M. Valyashko and Miroslav S. Gruszkiewicz 7.1 Batch techniques ...................................... 272 7.2 Flow techniques ....................................... 272 7.3 Summary table ......................................... 274 References .................................................... 284 Index ......................................................... 289