Materials syntheses: a practical guide / ed. by Schubert U., Husing N., Laine R. - Wien, New York: Springer, 2008. - vii, 228 p. - Incl. bibl. ref. and index. - ISBN 978-3-211-75124-4  Место хранения:   024 | Институт неорганической химии им. А.В.Николаева CO РАН | Новосибирск

Оглавление / Contents

Preface ......................................................... 1 List of Contributors ............................................ 3 Controlling Size and Morphology of Zeolite L .................... 9 Large Zeolite L Crystals .................................... 11 Medium-sized Disc-shaped Zeolite L Crystals ................. 13 Nano-sized Zeolite L Crystals ............................... 15 Medium-sized Cylindrical-shaped Zeolite L Crystals .......... 16 Zeolite A and ZK-4 ............................................. 21 Zeolite A Crystals .......................................... 25 ZK-4 Crystals ............................................... 26 Nano-sized Zeolite A Crystals (Fig. 4) ...................... 27 Mesostructured Silica Thin Films ............................... 29 Preparation of the Coating Sol .............................. 32 Film Deposition ............................................. 33 Post Treatment .............................................. 33 Organically Modified Monolithic Silica Aerogels ................ 39 Preparation of 3-Methacryloxypropyl-substituted Silica Aerogel ..................................................... 41 Preparation of 2-Aminoethyl-3-aminopropyl-substituted Silica Aerogel .............................................. 44 Porous Silica Gel by Acid Leaching of Metakaolin ............... 47 Preparation of Metakaolins .................................. 49 Preparation of the Acid-activated Solids .................... 49 Zirconia-Pillared Clays ........................................ 53 Preparation of Zr-pillared Clays Using Zirconyl Chloride as Precursor ................................................ 55 Preparation of Zr-pillared Clays Using Zirconium Acetate as Precursor ................................................ 57 Montmorillonites with Mixed Aluminum-Lanthanide Oxide Pillars ........................................................ 59 Preparation of the Pillaring Agent .......................... 60 Pillaring Process ........................................... 61 Birnessite-type Manganese Oxide by Redox Precipitation ......... 65 Redox Precipitation ......................................... 67 Hydrothermal Treatment ...................................... 68 Templated Carbon from Pyrolysis of Pyrene in Pillared Clay Matrices ....................................................... 71 Preparation of Pillared Clay ................................ 73 Loading of the Pillared Clay with Organic Compounds ......... 74 Pyrolysis, and Removal of the Inorganic Matrix .............. 75 Fiberous Carbon from Sepiolite Clay and Propylene .............. 77 Preparation of Propylene-loaded Sepiolite ................... 79 Pyrolysis and Dissolution of the Propylene-loaded Sepiolite ................................................... 81 Aerosol Spray Synthesis of Porous Molybdenum Sulfide Powder .... 83 Preparation of Low-porosity MoS2 ............................ 86 Preparation of Porous MoS2 .................................. 86 Sonochemically Prepared Molybdenum Sulfide ..................... 89 Preparation in Glove Box .................................... 91 Reaction in Fume Hood ....................................... 92 Product Isolation ........................................... 92 Doped Manganites ............................................... 95 Preparation of La0.5Ba0.5MnO3 ................................ 97 Preparation of La0.5Sr0.5MnO3 ............................... 100 Lithium Manganese Oxide Prepared by Flux Methods .............. 103 Growth of LiMn204 Spinel Single Crystals in a LiCl-Mn(NO3)2 Flux ......................................... 105 Growth of LiMn204 Spinel Single Crystals in a LiCl-MnCl2 Flux ....................................................... 107 Nanoscale Magnesium Oxide ..................................... 111 Nanostructured Pt-doped Tin Oxide Films ....................... 117 Preparation of Tetra(tert-butoxy)tin ....................... 119 Preparation of the Sol for Coating ......................... 119 Film Deposition and Annealing .............................. 121 Organically Functionalized Silica Nanoparticles ............... 127 Synthesis of SiO2 Nanoparticles ............................ 129 Preparation of 2-[4- (Chloromethyl)phenyl]ethyltriethoxysilane .................. 130 Functionalization of the Silica Particles .................. 130 Copper Nanoparticles in Silica ................................ 135 Sol-Gel Processing of Alkoxysilyl-substituted Metal Complexes .................................................. 138 Oxidation .................................................. 139 Reduction .................................................. 140 Copper Nanocrystals ........................................... 143 Assembly of TOPO-Capped Silver Nanoparticles to Multilayered Films ............................................ 149 Preparation of Silver Hydrosols ............................ 151 Transfer of the Silver Nanoparticle Sol into Organic Solvents ................................................... 151 Multilayered Film Synthesis ................................ 152 Colloidal Dispersion of Gold Nanoparticles .................... 155 Preparation of HAuCl4•3H20 .................................... 157 Preparation of Gold Nanoparticles Colloidal Suspension ..... 158 One-dimensional Nanorods and Nanowires ........................ 163 Preparation of Gold Seeds .................................. 164 Preparation of Growth Solution ............................. 164 Preparation of Gold Nanorods and Wires ..................... 165 Monolithic Tin-doped Silica Glass ............................. 169 Sol Preparation ............................................ 171 Sol-Gel Transition and Drying .............................. 171 Thermal Treatment and Glass Formation ...................... 172 Sintering Process A ........................................ 172 Sintering Process В ........................................ 173 Octaphenyloctasilsesquioxane and Polyphenylsilsesquioxane for Nanocomposites ............................................ 179 Synthesis of Phenyltriethoxysilane (PTES) .................. 182 Synthesis of OPS and its Polymeric Analog PPS from PTES .... 182 PoIysilsesquicarbodiimide Xerogels ............................ 193 Polyaniline - A Conducting Polymer ............................ 199 Preparation of Polyaniline Hydrochloride ................... 201 Preparation of Polyaniline Base ............................ 204 Allyl- and Hydroxytelechelic Poly(isobutylenes) ............... 209 Syntheses of Ally 1-telechelic P1B (1) ..................... 213 Syntheses of Hydroxy 1-telechelic PIBs (2) ................. 215 Symmetrically and Unsymmetrically Substituted Phthalocyanines ............................................... 217 Procedure A ................................................ 221 Procedure В ................................................ 223 Index ......................................................... 227