 | Plastics for corrosion inhibition / Goldade V.A., Pinchuk L.S., Makarevich A.L., Kestelman V.N. - Berlin; Heidelberg: Springer, 2005. - xii, 383 p. - (Springer series in materials science; 82). - ISBN 30540-2384902; ISSN 0933-033X
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1. Design Principles of Plastics Containing Metal
Corrosion Inhibitors .......................................... 1
1.1. Underlying Notions ......................................... 2
1.1.1. Corrosion of Metals ................................. 2
1.1.2. Composite Plastics .................................. 8
1.1.3. Friction of Inhibited Plastics ..................... 11
1.2. Corrosion Processes in Metal-Polymer Contacts ............. 13
1.2.1. Corrosion Specifics at the Metal-Polymer
Interface .......................................... 14
1.2.2. Polymer Materials as a Source of Corrosion
Agents ............................................. 16
1.2.3. Polymer Effect
on Electrochemical Polarization Kinetics of
Metals ............................................. 19
1.2.4. Permeability of Polymers to Electrolytes ........... 21
1.3. Components of Inhibited Plastics .......................... 24
1.3.1. Binders for Inhibited Plastics ..................... 25
1.3.2. Corrosion Inhibitors ............................... 27
1.3.3. Other Ingredients of Inhibited Plastics ............ 42
1.4. Thermodynamic and Process Compatibility
of the Components of Inhibited Plastics ................... 46
1.4.1. Phase Equilibrium in Polymer-Solvent Systems ....... 47
1.4.2. Compatibility of Components of Inhibited
Plastics and Its Regulation ........................ 51
1.5. Manufacturing Methodology
of Inhibited Plastics ..................................... 58
1.5.1. Mass Transfer of Inhibitors
within the Anticorrosion System ........................... 59
1.5.2. Processes of Combining Polymers and Inhibitors ..... 62
1.6. Estimation Procedures of Inhibited Plastics Efficiency .... 65
1.7. Designation of Inhibited Plastics ......................... 72
References ................................................ 75
2. Films Incorporating Corrosion Inhibitors .................... 81
2.1. Classification ............................................ 82
2.2. Production Methods ........................................ 94
2.2.1. Principles of Manufacturing Inhibited Films ........ 94
2.2.2. Basic Production Techniques of Polymer Films ....... 94
2.2.3. Methods of Combining Corrosion Inhibitors
with Polymer Films ................................. 97
2.2.4. Manufacture of Inhibited Films by Hose Extrusion ... 99
2.2.5. Some Other Methods of Manufacturing Inhibited
Films ............................................. 110
2.2.6. Monitoring of Corrosion Inhibitors Absorption
by Films Using Physical Fields .................... 113
2.3. Structure, Properties and Protection Mechanism ........... 121
2.3.1. Structural Peculiarities of Inhibited Film
Materials ......................................... 122
2.3.2. The Main Functional Properties
of Inhibited Films ................................ 125
2.3.3. Anticorrosion Mechanism ........................... 141
2.4. Quality Control .......................................... 153
2.5. Fields of Application .................................... 156
2.5.1. Methods of Packing into Inhibited Films ........... 157
2.5.2. Application of Inhibited Films in Sealing
Systems ........................................... 162
References .................................................... 165
3. Inhibited Coatings ......................................... 175
3.1. Polymer Coatings as Elements of Anticorrosion Systems .... 176
3.1.1. Electrode Potentials .............................. 176
3.1.2. Polarization Characteristics ...................... 178
3.1.3. Electrical Resistance ............................. 180
3.1.4. Capacity .......................................... 183
3.1.5. Diffusion Characteristics ......................... 184
3.1.6. Self-Passivation .................................. 190
3.2. Modern Trends in Coating Design .......................... 192
3.2.1. Electret Coatings ................................. 193
3.2.2. Electroconductive Coatings ........................ 197
3.2.3. Inhibited Coatings ................................ 202
3.3. Coating Techniques ....................................... 206
3.3.1. Deposition of Powder Coatings on Heated Ware ...... 206
3.3.2. Deposition of Polymer Melts ....................... 213
3.3.3. Electrostatic Deposition of Powder Coatings ....... 218
3.3.4. Liquid-Induced Modification of Powder Coatings .... 226
3.4. Adhesion ................................................. 229
3.5. The Range of Inhibited Coatings .......................... 233
3.5.1. Paint-and-Varnish Coats ........................... 233
3.5.2. Powder Coatings ................................... 238
3.5.3. Coats Based on Adhesive Tapes ..................... 241
3.5.4. Preservative Coats ................................ 244
References .................................................... 247
4. Structural Inhibited Plastics .............................. 255
4.1. Corrosive Wear of Metals ................................. 255
4.1.1. Chemical and Oxidative Wear ....................... 257
4.1.2. Metal Failure in Electrolytes
Under Mechanical Stresses ......................... 259
4.1.3. Electrochemical Processes During Friction ......... 263
4.1.4. Mechanochemical Kinetics of Metal Wear ............ 265
4.1.5. Means of Inhibiting Mechanochemical Wear
in Polymer-Metal Pairs ............................ 269
4.2. Electrical Processes
in Movable Metal-Polymer Contacts ........................ 272
4.2.1. Electrization and Polarization
of Polymers During Friction ....................... 272
4.2.2. Thermally Stimulated Currents
in Metal-Polymer-Metal Systems .................... 276
4.2.3. Metal Corrosion and Wear in Contact
with Metal-Polymer Electrets ...................... 282
4.2.4. Wear Inhibiting by Electrical Fields .............. 288
4.3. Tribochemical Processes in Metal-Polymer Contacts ........ 294
4.3.1. Tribochemical Transformations in Polymers ......... 294
4.3.2. Tribochemical Transformations in
Polymer-Metal Systems ............................. 299
4.3.3. The Mechanochemical Concept of Wear of
Metal-Polymer Friction Pairs ...................... 302
4.4. Suppression of Mechanochemical Wear
of Metals by Inhibited Plastics .......................... 307
4.4.1. Structure and Properties of Inhibited Plastics .... 307
4.4.2. The Effect of Corrosion Inhibitors
on Thermal Oxidation of Polymers .................. 311
4.4.3. The Kinetics of Electrochemical Processes
During Friction of Inhibited Plastics ............. 312
4.4.4. Wear Resistance of Inhibited Plastics ............. 315
4.5. Inhibited Antifrictional Materials ....................... 316
4.5.1. Compositions and Properties ....................... 317
4.5.2. Processing Into Goods ............................. 321
4.5.3. Application ....................................... 325
References .................................................... 328
5. Inhibited Engineering Service Materials .................... 337
5.1. Glues .................................................... 337
5.2. Sealants ................................................. 339
5.3. Plastic Carriers of Inhibitors ........................... 342
5.4. Inhibited Plastic Containers ............................. 344
5.5. Microcapsules ............................................ 347
References .................................................... 350
6. Economic and Social Aspects of Adoption
of Inhibited Plastics ...................................... 353
6.1. Cost-Effectiveness ....................................... 353
6.2. Safety Measures .......................................... 360
6.2.1. Toxicology ........................................ 360
6.2.2. Labour Protection and Fire Safety ................. 365
6.3. Production and Application Ecology ....................... 368
References .................................................... 371
Index ......................................................... 377
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