Preface ......................................................... v
Program Committee ............................................. vii
Organizing Committee .......................................... vii
International Scientific Advisory Board ...................... viii
Financial Support .............................................. ix
I. Catalytic combustion
1. Catalytic combustion of methane over
Pd/SBA-15/А12O3/FeCrА1 catalysts
Fengxiang Yin, Shengfu Ji, Fuzhen Zhao, Zhongliang
Zhou and Chengyue Li ..................................... 1
2. Catalytic Combustion of Methane over
PdO-Ce02/Al203 and PdO-Ce02/Zr02 catalysts
Daniela Domingos, Lilian M.T.Simplicio, Genic leide
S.Estrela, Marcionila A.G. dos Prazeres and Soraia
T.Brandão ................................................ 7
II. Direct conversion of methane to oxygenates, olefins
and aromatics
3. Methane conversion to chemicals, carbon and
hydrogen (MCCH) over modified molybdenum-NAS
catalysts
M.W.Ngobeni, M.S.Scurrell and C.P.Nicolaides ............ 13
4. Oxidative coupling of methane in a catalytic
membrane reactor: Impact of the catalyst-membrane
interaction on the reactor performance
Stephane Haag, Magdalena Bosomoiu, Andre C. van Veen
and Claude Mirodatos .................................... 19
5. Characterization of Mo/ZSM-11 and Mo-Ru/ZSM-11
catalysts. Effect of Mo content and Ru addition
on the nature of Mo species
Renata L.Martins, Luiz E.P.Borges and Fabio
B.Noronha ............................................... 25
6. Conversion of methane to benzene via oxidative
coupling and dehydroaromatization
J.S.Espindola, N.R.Marcilio and O.W.Perez-Lopez ......... 31
7. Bimetallic orthophosphate and pyrophosphate catalysts
for direct oxidation of methane to formaldehyde
Magdaléna Štolcová, Christian Litterscheid,
Milan Hronec and Robert Glaum Financial Support ......... 37
III Energy production from natural gas
8. IT-SOFC operated with catalytically processed
methane fuels
Baofeng Tu, Yonglai Dong, Mojie Cheng, Zhijian
Tian and Qin Xin Financial Support ...................... 43
IV FT synthesis of hydrocarbons
9. Activity and stability of iron based catalysts
in advanced Fischer-Tropsch technology via
C02-rich syngas conversion
L.Spadaro, F.Arena, G.Bonura, O.Di Blasi and
F.Frusteri .............................................. 49
10. Highly active cobalt-on-silica catalysts for the
Fischer-Tropsch synthesis obtained via a novel
calcination procedure
Jelle R.A.Sietsma, Johan P. den Breejen, Petra
E.de Jongh, A.Jos van Dillen, Johannes H.Bitter and
Krijn P. de Jong ........................................ 55
11. Intensification of Commercial Slurry Phase Reactors
Alex Vogel, Andre Steynberg and Berthold Breman ......... 61
12. A Hydrodynamic Experimental Study of Slurry Bubble
Column
Behnoosh Moshtari, Jafar Sadegh Moghaddas and
Ensieh Gangi ............................................ 67
13. H-ZSM-5/cobalt/silica capsule catalysts with
different crystallization time for direct synthesis
of isoparaffins: simultaneous realization of space
confinement effect and shape selectivity effect
Guohui Yang, Jingjiang He, Yoshiharu Yoneyama
and Noritatsu Tsubaki Financial Support ................. 73
14. Fischer-Tropsch catalyst deposition on metallic
structured supports
L.C.Almeida, O.González, O.Sanz, A.Paul,
M.A.Centeno, J.A.Odriozola and M.Montes ................. 79
15. On the origin of the cobalt particle size effect
in the Fischer-Tropsch synthesis
P.B.Radstake, J.P. den Breejen, G.L.Bezemer,
J.H.Bitter, K.P. de Jong, V.Frøseth and A.Holmen ........ 85
16. Modification of cobalt catalyst selectivity
according to Fischer-Tropsch process conditions
Marie-Claire Marion and François Hugues ................. 91
17. Effect of water on the deactivation of coprecipitated
Co-Zr02 catalyst for Fischer-Tropsch Synthesis
Lihong Shi, Jiangang Chen, Kegong Fang and
Yuhan Sun ................................................ 97
18. Effect of preparation methods on the catalytic
properties of Co/SBA-15 catalysts for
Fischer-Tropsch synthesis
Yuelun Wang, Jiangang Chen, Kegong Fang and
Yuhan Sun .............................................. 103
19. Influence of pretreatment on the catalytic
performances of Co-ZrCb catalysts for
Fischer-Tropsch synthesis
Litao Jia, Kegong Fang, Jiangang Chen and Yuhan Sun .... 111
20. Fischer-Tropsch synthesis. Recent studies on the
relation between the properties of supported
cobalt catalysts and the activity and selectivity
Øyvind Borg, Vidar Frøseth, Sølvi Stors ter,
Erling Rytter and Anders Holmen ........................ 117
21. Patenting Trends in Natural Gas Fischer-Tropsch
Synthesis
Adelaide Antunes, Maria Simone Alencar,
Fernando Tibau, Daniel Hoefle, Andressa Gusmão,
Angela Ribeiro and Rodrigo Cartaxo ..................... 123
22. Cobalt Supported on Different Zeolites for
Fischer-Tropsch Synthesis
Andreia S.Zola, Antônio M.F.Bidart,
Adriano do C.Fraga Carla E.Hori, Eduardo
E.Sousa-Aguiar and Pedro A.Arroyo ...................... 129
23. Production of liquid hydrocarbons employing Natural
Gas: a study of the technical and economical
feasibility of a GTL plant in Brazil
Roberto Callari, Tatiana Magalhães Gerosa and
Patricia Helena Lara dos Santos Matai .................. 135
24. New Supports for Co-based Fischer-Tropsch Catalyst
A.F.Costa, H.S.Cerqueira, E.Falabella S.Aguiar,
J.Rollán and A.Martinez ................................ 141
25. Fischer-Tropsch synthesis on Pd-Co/Nb205
catalysts
Carlos Darlan de Souza, D.V.Cesar, S.G.Marchetti
and M.Schmal ........................................... 147
V. H2 production to fuel cells
26. Methane Conversion for Fuel Cells. The Role of
Sulphur
J.R.Rostrup-Nielsen .................................... 153
27. Experimental Demonstration of H2 Production by C02
Sorption Enhanced Steam Methane Reforming Using Ceramic
Acceptors
Esther Ochoa-Fernández, Claudia Lacalle-Vilá, Tiejun
Zhao, Magnus Rønning and De Chen ....................... 159
28. Effect of support on autothermal reforming of methane
on nickel catalysts
Juliana da Silva Lisboa, Mônica Pinto Maia,
Ana Paula Erthal Moreira and Fabio Barboza Passos ...... 165
29. Selective CO removal in the H2-rich stream
through a double-bed system composed of
non-noble metal catalysts
Yun Ha Kim, Eun Duck Park, Hyun Chul Lee, Rang Hee
Lee and Soonho Kim ..................................... 171
30. Hydrogen Production by Steam Reforming of Natural
Gas over Highly Stable Ru Catalyst Supported on
Nanostructured Alumina
Hyun Chul Lee, Yulia Potapova, Ok Young Lim, Doohwan
Lee, Soonho Kim, Jae Hyun Park and Eun Duck Park ....... 177
31. Heat effects in a membrane reactor for the water gas
shift reaction
M.E.Adrover, E.López, D.O.Borio and M.N.Pedernera ...... 183
32. Au/ZnO and the PROX REACTION
Kátia R.Souza, Adriana F.F. de Lima, Fernanda
F.de Sousa and Lucia Gorenstin Appel ................... 189
33. Selective Catalytic Oxidation of CO in H2 over
Copper-Exchanged Zeolites
Ivana Tachard, Anna C.B. da Silva, Fábio Argolo,
Suzana M.O.Brito, Heloise O.Pastore, Heloysa
M.C.Andrade and Artur J.S.Mascarenhas .................. 195
34. ZrO2-supported Pt Catalysts for Water Gas
Shift Reaction and Their Non-Pyrophoric Property
Hyun Chul Lee, Doohwan Lee, Ok Young Lim, Soonho Kim,
Yong Tae Kim, Eun-Yong Ko, Eun Duck Park ............... 201
35. Steam reforming of natural gas on noble-metal based
catalysts: Predictive modeling
Benjamin T.Schädel and Olaf Deutschmann ................ 207
36. Activity of Cu/Ce02 and Cu/Ce02-Zr02
for low temperature water-gas shift reaction
André L.M. da Silva and Losé M.Assaf ................... 210
37. Hydrogen separation from the mixtures in a thin
Pd-Cu alloy membrane reactor
Xiaoliang Zhang, Guoxing Xiong and Weishen Yang ........ 219
38. Effect of cobalt on the activity of iron-based
catalysts in water gas shift reaction
Amalia L.C.Pereira, Nilson A. dos Santos, Márcio
L.O.Ferreira, Alberto Albornoz and Maria do Carmo
Rangel ................................................. 225
VI. Natural gas to chemicals
39. The role of carbon nanospecies in deactivation
of cobalt based catalysts in CH4
and CO transformation
L.Borkó, Z.E.Horváth, Z.Schay and L.Guczi ............. 231
40. Effective and stable Ce02-W-Mn/Si02 catalyst
for methane oxidation to ethylene and ethane
Bing Zhang, Jiaxin Wang, Lingjun Chou,
Huanling Song, Jun Zhao, Jian Yang and Shuben Li ....... 237
41. Very Large Scale Synthesis Gas Production and
Conversion to Methanol or Multiple Products
Kim Aasberg-Petersen, Charlotte Stub Nielsen
and Ib Dybkiver ........................................ 243
42. Autothermal Reforming of Methane under low
Steam/Carbon ratio on supported Pt Catalysts
Juan A.C.Ruiz, Fabio B.Passos, José M.C.Bueno,
E.F.Souza-Aguiar, Lisiane V.Mattos and Fabio
B.Noronha .............................................. 249
43. Conversion of natural gas to higher valued products:
light olefins production from methanol over ZSM-5
zeolites
Zilacleide da Silva Barros, Fátima Maria Zanon
Zotin and Cristiane Assumpção Henriques ................ 255
44. Lurgi's Methanol to Propylene (MTP) Report on
a successful Commercialisation
Harald Koempel and Waldemar Liebner .................... 261
VII. Production of synthesis gas
45. Partial oxidation of hydrocarbon gases as a base
for new technological processes in gas and power
production
Vladimir S.Arutyunov ................................... 269
46. Effect of chemical treatment on Ni/fly-ash
catalysts in methane reforming with carbon dioxide
Shaobin Wang and G.Q.Lu ................................ 275
47. Kinetic Depressing the Deposition of Carbon
Species on Ni-Based Catalysts: La2O3 Adjusts
the Reaction Rates of CO2 Higher than CH4
by Tuning the Ea and Pre-exponential Factor
Yuehua Cui, Huidong Zhang, Hengyong Xu, Qingjie
Ge, Yuzhong Wang, Shoufu Hou and Wenzhao Li ............ 281
48. Investigation of unsteady-state redox mechanisms
over ceria based catalysts for partial oxidation
of methane
C.Mirodatos, Y.Schuurman, A.C. van Veen,
V.A. Sadykov, L.G.Pinaeva, E.M.Sadovskaya .............. 287
49. Investigation by high throughput experimentation of
ceria based catalysts for H2 purification and CO2
reforming of CH4
J.Despres, C.Daniel, D.Farrusseng, A.C. van Veen,
C.Mirodatos ............................................ 293
50. A Carbon Reaction Pathway for Dimethyl Ether,
Methanol and Methane from Syngas on an Alumina
Supported Palladium Catalyst
Masood Otarod and Sami H.Ali ........................... 299
51. Low Emission Conversion of Natural Gas to Hydrogen
D.Trimm, I.Campbell, Y.Lei, N.Assanee and
N.W.Cant ............................................... 307
52. SiC as stable high thermal conductive catalyst for
enhanced SR process
F.Basile, P.Del Gallo, G.Fornasaria, D.Gary,
V.Rosetti and A.Vaccari ................................ 313
53. Catalytic partial oxidation of CH4 and C3H8:
experimental and modeling
study of the dynamic and steady state behavior of
a pilot-scale reformer
Ivan Tavazzi, Alessandra Beretta, Gianpiero Groppi,
Alessandro Donazzi, Matteo Maestri, Enrico Tronconi,
Pio Forzatti ........................................... 319
54. Additive effect of 02 on propane catalytic
dehydrogenation to propylene over Pt-based catalysts
in the presence of H2
Changlin Yu, Hengyong Xu, Qingjie Ge
and Wenzhao Li ......................................... 325
55. Au/Ti02 as a catalyst for the selective
hydrogen combustion (SHC) applied to the catalytic
dehydrogenation of propane
Hilde Dyrbeck and Edd A. Blekkan ....................... 331
56. Oxidative dehydrogenation of ethane at short contact
times
Silje F.Håkonsen and Anders Holmen ..................... 337
57. Study of synthesis gas production over structured
catalysts based on LaNi(Pt)Ox- and Pt(LaPt)-
Ce02-Zr02 supported on corundum
S.N.Pavlova, N.N.Sazonova, V.A.Sadykov, G.M.Alikina,
A.I.Lukashevich, E.Gubanova and R.V.Bunina ............. 343
58. Direct synthesis of Propane/Butane from synthesis
gas
Kaoru Fujimoto, Hiroshi Kaneko, Qianwen Zhang,
Qingjie Ge and Xiaohong Li ............................. 349
59. LPG Synthesis from DME with semi-direct method
Wenliang Zhu, Xiaohong Li, Hiroshi Kaneko and Kaoru
Fujimoto ............................................... 355
60. Performance of monolithic catalysts with complex
active component in partial oxidation of methane
into syngas: experimental studies and modeling
V.Sadykov, S.Pavlova, Z.Vostrikov, N.Sazonova,
E.Gubanova, R.Bunina, G.Alikina, A.Lukashevich,
L.Pinaeva, L.Gogin, S.Pokrovskaya, V.Skomorokhov,
A.Shigarov, C.Mirodatos, A. van Veen,
A.Khristolyubov and V.Ulyanitskii ...................... 361
61. C02 reforming of methane to syngas over
Ni/SB A-15/FeCrAl catalyst
Kai Wang, Xiujin Li, Shengfu Ji., Si Sun, Dawei
Ding, and Chengyue Li .................................. 367
62. Scale-up Challenges in Synthesis Gas Production
Soren Gyde Thomsen, Olav Holm-Christensen
and Thomas S.Christensen ............................... 373
63. Studies of Carbon Deposition over Rh-Ce02/Al203 during
CH4/C02 Reforming
Rui Wang, Xuebin Liu, Qingjie Ge, Wenzhao Li
and Hengyong Xu ........................................ 379
64. Development of C02 Reforming
Technology
Fuyuki Yagi, Shinya Hodoshima, Shuhei Wakamatsu,
Ryuichi Kanai, Kenichi Kawazuishi, Yoshifumi Suehiro,
Mitsunori Shimura ...................................... 385
65. The optimization of preparation, reaction
conditions and synthesis gas production by
redox cycle using lattice oxygen
Xiaoping Dai, Changchun Yu., Ranjia Li and
Zhengping Hao .......................................... 391
66. Effect of Rh addition on activity and stability
over Ni/γ-Al2O3 catalysts
during methane reforming with C02
Marco Ocsachoque, Claudia E. Quincoces, M. Gloria
González ............................................... 397
67. Slurry Phase DME Direct Synthesis Technology-100
tons/day Demonstration Plant Operation and Scale
up Study
Yotaro Ohio, Hiroshi Yagi, Norio Inoue, Keiichi
Okuyama and Seiji Aoki ................................. 403
68. The performance of Pt/CeZr02/Al203
catalysts on the partial oxidation and autothermal
reforming of methane
Vanessa B.Mortola, Juan A.C.Ruiz, Diego da
S.Martinez, Lisiane V.Mattos, Fa'bio B.Noronha,
Carla E.Hori ........................................... 409
69. Development of monolith catalyst for catalytic partial
oxidation of methane
Kenichi Imagawa, Atsuo Nagumo, Ryuichi Kanai,
Takeshi Minami, Keiichi Tomishige, Yoshifumi
Suehiro ................................................ 415
70. Promoter effect of Ag and La on stability of Ni/Al203
catalysts in reforming of methane processes
N.V.Parizotto, R.F.Fernandez, C.M.P.Marques
and J.M.C.Bueno ........................................ 421
71. The Effect of Pt Loading and Space Velocity on the
Performance of Pt/CeZr02/Al203
Catalysts for the Partial Oxidation of Methane
Fabiano de A.Silva, Diego da S.Martinez, Juan
A.C.Ruiz, Lisiane V.Mattos, Fabio B.Noronha,
Carla E.Hori ........................................... 427
72. Promoter effect of Ce02 on the stability
of supported Pt catalysts for methane-reforming as
revealed by in-situ XANES and TEM analysis
A.P.Ferreira, J.C.S.Araújo, J.W.C.Liberatori,
S.Damyanova, D.Zanchet, F.B.Noronha and
J.M.C.Bueno ............................................ 433
73. Advanced Auto-thermal Gasification Process
Yoshiyuki Watanabe, Nobuhiro Yamada, Akira Sugimoto,
Koichiro Ikeda, Naoki Inoue, Fuyuki Noguchi
and Yoshifumi Suehiro .................................. 439
74. Bifunctional Catalysts for Hydrogen Production from
Dimethyl Ether
Galina Volkova, Sukhe Badmaev, Vladimir Belyaev,
Lyudmila Plyasova, Anna Budneva, Evgeny Paukshtis,
Vladimir Zaikovsky and Vladimir Sobyanin ............... 445
75. Autothermal reforming of methane over nickel
catalysts prepared from hydrotalcite-like compounds
Mariana M.V.M.Souza, Nielson F.P.Ribeiro,
Octávio R.Macedo Neto, Ivna O.Cruz and
Martin Schmal .......................................... 451
76. A high effective catalytic system for the
production of synthesis gas for gas-to-liquid
Shizhong (Jason) Zhao, X.D. Hu, David Rogers,
David Tolle ............................................ 457
77. Conversion of methanol to hydrocarbons: Hints to
rational catalyst design from fundamental
mechanistic studies on H-ZSM-5
Morten Bjorgen, Karl-Petter Lillerud, Unni Olsbye
and Stian Svelle ....................................... 463
78. Dry Reforming and Partial Oxidation of Natural Gas
to Syngas Production
Leonardo José Lins Maciel, Aleksándros El
Áurens Meira de Souza, Solange Maria
de Vasconcelos, Augusto Knoechelmann and Cesar
Augusto Moraes de Abreu ................................ 469
79. Preparation of Ni/Si02, Ni/Si02-CaO
and Ni/Si02-MgO catalysts for methane steam
reforming
Alano V.da Silva Neto, Patricia P.C.Sartoratto
and Maria do Carmo Rangel .............................. 475
80. Perovskites as catalyst precursors: partial oxidation
of methane on La1-xCaxNiO3
S.M. de Lima, M.A.Pena, J.L.G.Fierro and J.M.Assaf ..... 481
81. Ni/CeZr02-based catalysts for H2
production
Sandra C.Dantas, Janaina C.Escritori, Ricardo
R.Soares and Carla E.Hori .............................. 487
82. Effect of aluminum content on the properties
of lanthana-supported nickel catalysts to WGSR
Manuela de S. Santos, Guillermo Paternina
Berrocala, José Lui's Garcia Fierro, Maria do
Carmo Rangel ........................................... 493
83. Evaluation of Pd/La203 catalysts
for dry reforming of methane
Luiz Carlos P.Fernandes Júnior, Sergio de Miguel,
José Luis Garcia Fierro and Maria do Carmo Rangel ...... 499
84. SNOW: Styrene from Ethane and Benzene
Domenico Sanfilippo, Guido Capone, Alberto Cipelli,
Richard Pierce, Howard Clark and Matt Pretz ............ 505
85. Designing Pt catalysts by sol-gel chemistry:
influence of the Pt addition methods on catalyst
stability in the partial oxidation of methane
A.P.Ferreira, V.B.Mortola, R.Rinaldi, U.Schuchardt
and J.M.C.Bueno ........................................ 511
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