 | Liao G. Solid electrolyte based structural supercapacitors: Diss. … Dr.-Ing. / Institut für Faserverbundleichtbau und Adaptronik, Braunschweig. – Köln: DLR, 2018. - XIX, 131 p.: ill., tab. - (Forschungsbericht; 2018-17). - Res. also Germ. - Bibliogr.: p.106-116.
- ISSN 1434-8454
Шифр: (Pr 1120/2018-17) 02
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ABSTRACT ........................................................ 1
ACKNOWLEDGEMENTS ................................................ V
TABLE OF CONTENTS .............................................. VI
NOMENCLATURES ................................................ VIII
LIST OF FIGURES ................................................ XI
LIST OF TABLES ................................................ XIX
Chapter 1 Introduction .......................................... 1
1.1 Motivation ................................................. 1
1.2 Structural storage devices ................................. 1
1.3 Solid electrolyte .......................................... 2
1.4 Aims of the present work ................................... 2
1.5 Outline of the thesis ...................................... 3
Chapter 2 Background and Hypotheses ............................. 5
2.1 Basic of EDLCs ............................................. 5
2.2 Structural capacitor and supercapacitor .................... 8
2.3 Fast ion conductor as solid electrolyte ................... 10
2.4 Carbon Nanotube (CNT) as electrode ........................ 15
2.5 Solid state ionic theory for ionic conductor based
supercapacitor ............................................ 17
2.6 Configuration design of structural supercapacitors ........ 18
2.7 Hypotheses ................................................ 20
Chapter 3 Measurements and Manufactures ........................ 21
3.1 Microstructure characterizations .......................... 21
3.2 Electrical measurements ................................... 23
3.3 Mechanical tests .......................................... 32
3.4 Manufacture of specimens and setup of measurements ........ 36
Chapter 4 LATP Solid Electrolyte Based Structural Capacitors ... 43
4.1 LATP solid electrolyte .................................... 43
4.2 Multifunctional properties ................................ 51
4.3 Challenges and improvements of integration ................ 63
Chapter 5 Carbon Nanotube Based Electrode for Structural
Supercapacitors ................................................ 74
5.1 Microstructure characterization ........................... 75
5.2 Supercapacitive behavior described by CV .................. 78
5.3 Two-layer configuration with SWCNTs ....................... 78
5.4 Three-layer configuration with SWCNTs ..................... 82
5.5 Influence of SWCNTs' addition on integration .............. 93
5.6 Feasibility of solid supercapacitors with MWCNTs .......... 98
Chapter 6 Conclusions and Outlooks ............................ 103
6.1 Performance evaluation ................................... 103
6.2 Conclusions .............................................. 103
6.3 Outlooks ................................................. 105
Reference ..................................................... 106
Appendix A .................................................... 118
Appendix В .................................................... 126
Appendix С .................................................... 130
Appendix D .................................................... 131
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