Chen S.-H. Scattering methods in complex fluids (Cambridge, 2015). - ОГЛАВЛЕНИЕ / CONTENTS
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ОбложкаChen S.-H. Scattering methods in complex fluids: selected topics / S.-H.Chen, P.Tartaglia. - Cambridge: Cambridge University Press, 2015. – xvii, 382 p.: ill. – Ref.: p.359-377. – Ind.; p.379-382. – ISBN 978-0-521-88380-1
Шифр: (И/В36-С51) 02
 

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Оглавление / Contents
 
List of illustrations .......................................... ix
Preface ........................................................ xv

Part I  Scattering and liquids .................................. 1
1  Scattering techniques for the liquid state ................... 3
   1.1  Introduction ............................................ 3
   1.2  Module - Small angle neutron scattering ................ 28
2  Statistical mechanics of the liquid state ................... 48
   2.1  Pair correlations and structure factors in liquids ..... 49
   2.2  The Ornstein-Zernike equation and its approximate 
        solutions .............................................. 66
   2.3  Theories of macroion solutions ......................... 80
3  Aggregation and cluster formation ........................... 88
   3.1  Introduction ........................................... 88
   3.2  Module - Reaction controlled aggregation of colloidal 
        particles .............................................. 92
   3.3  Module - Diffusion controlled irreversible 
        aggregation and supramolecular ordering ............... 101
   3.4  Module - Percolation in microemulsions ................ 109
   3.5  Module - Critical supramolecular systems .............. 114
   
Part II  Structural arrest .................................... 125
4  The theory of slow dynamics in supercooled colloidal 
   solutions .................................................. 127
   4.1  Introduction .......................................... 127
   4.2  Module - The mode-coupling theory of supercooled
        liquids ............................................... 131
   4.3  Module - MCT for repulsive and attractive glasses ..... 139
   4.4  Module - Clustering in systems with competing 
        interactions .......................................... 151
5  Experiments on structural arrest ........................... 157
   5.1  Introduction .......................................... 157
   5.2  Module - Experiments on the glass transition in PMMA .. 158
   5.3  Module - Copolymer solutions and higher-order 
        singularities ......................................... 160
   5.4  Module - The glass-glass transition ................... 166
6  Models of gel-forming colloids ............................. 179
   6.1  Introduction .......................................... 179
   6.2  Module - Limited valence models ....................... 182
   6.3  Module - Patchy colloids and Wertheim theory .......... 184
   6.4  Module - Gel-forming colloids and network glass
        formers ............................................... 194
   
Part III  Water ............................................... 209
7  Dynamic crossover phenomena in confined water .............. 211
   7.1  Introductory remarks on confined water ................ 211
   7.2  Module - Model for water's single-particle
        dynamics-relaxing cage model (RCM) .................... 224
   7.3  Module - Dynamic crossover in hydration water of
        biomaterials .......................................... 228
   7.4  Module - Dynamic crossover in hydration water of
        cement pastes ......................................... 249
   7.5  Module - Dynamic crossover in confined water and its
        relation to the second critical point of water ........ 252
   7.6  Module - Density measurement of confined water
        inMCM-41S ............................................. 258
8  Dynamic crossover phenomena in other glass-forming
   liquids .................................................... 274
   8.1  Introduction .......................................... 274
   8.2  Absence of structural arrest at Tg .................... 281
   8.3  Fractional Stokes-Einstein relation ................... 283
9  Inelastic neutron scattering in water ...................... 286
   9.1  Introduction to Q-dependent density of states 
        Gs(Q, ω) of water ..................................... 286
   9.2  Density of state measurements of water: a plausible 
        evidence for the existence of a liquid-liquid phase
        transition in low-temperature water ................... 293
   9.3  Measuring boson peak as a means to explore the 
        existence of the liquid-liquid transition in deeply
        cooled confined water ................................. 301
10 Introduction to high-resolution inelastic X-ray 
   scattering spectroscopy .................................... 309
   10.1 Comparison of inelastic neutron scattering and 
        inelastic X-ray scattering techniques ................. 309
   10.2 Module - Theory of inelastic X-ray scattering from
        monoatomic liquids .................................... 324
   10.3 Module - Finite Q collective modes in bio-
        macromolecular assemblies ............................. 336
References .................................................... 359
Index ......................................................... 379

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