The rare earth elements: fundamentals and applications / ed. by D.A.Atwood. - Chichester: Wiley, 2012. - xiv, 606 p.: ill. - (EIBC books). - Incl. bibl. ref. - Ind.: p.575-606. - ISBN 978-1-119-95097-4  Место хранения:   024 | Институт неорганической химии им. А.В.Николаева CO РАН | Новосибирск

Оглавление / Contents

Contributors ................................................... xi Series Preface ................................................. xv Volume Preface ............................................... xvii Geology, Geochemistry, and Natural Abundances of the Rare Earth Elements .................................................. 1 Scott M. McLennan and Stuart Ross Taylor Sustainability of Rare Earth Resources ......................... 21 David A. Atwood The Electronic Structure of the Lanthanides .................... 27 Ana de Bettencourt-Dias Variable Valency ............................................... 35 Andrew W.G. Platt Group Trends ................................................... 43 Andrew W.G. Platt Solvento Complexes of the Lanthanide Ions ...................... 55 Simon A. Cotton and Jack M. Harrowfield Lanthanides in Living Systems .................................. 65 Simon A. Cotton and Jack M. Harrowfield Lanthanides: Coordination Chemistry ............................ 73 Simon A. Cotton and Jack M. Harrowfield Organometallic Chemistry Fundamental Properties ................ 83 Stephen T. Liddle Lanthanides: "Comparison to 3d Metals" ........................ 105 Simon A. Cotton Luminescence .................................................. 111 Julien Andres and Anne-Sophie Chauvin Lanthanides: Luminescence Applications ........................ 135 Julien Andres and Anne-Sophie Chauvin Magnetism ..................................................... 153 Bing-Wu Wang and Song Gao The Divalent State in Solid Rare Earth Metal Halides .......... 161 Gerd Meyer Lanthanide Halides ............................................ 175 Timothy J. Boyle and Leigh Anna M. Steele Lanthanide Oxide/Hydroxide Complexes .......................... 183 Zhiping Zheng Lanthanide Alkoxides .......................................... 197 Timothy J. Boyle and Leigh Anna M. Steele Rare Earth Siloxides .......................................... 205 Clemens Krempner and Brian McNerney Thiolates, Selenolates, and Tellurolates ...................... 215 John G. Brennan Carboxylate ................................................... 225 Jia-sheng Lu and Ruiyao Wang Lanthanide Complexes with Amino Acids ......................... 237 Zhiping Zheng β-Diketonate .................................................. 249 Ke-Zhi Wang Rare Earth Borides, Carbides and Nitrides ..................... 263 Takao Mori Lanthanide Complexes with Multidentate Ligands ................ 281 Xiaoping Yang, Richard A. Jones and Wai-Kwok Wong Alkyl ......................................................... 299 Simon A. Cotton Aryls ......................................................... 303 Simon A. Cotton Trivalent Chemistry: Cyclopentadienyl ......................... 307 Roman A. Kresinski Tetravalent Chemistry: Inorganic .............................. 313 Farid M.A. Sroor and Frank T. Edelmann Tetravalent Chemistry: Organometallic ......................... 321 Farid M.A. Sroor and Frank T. Edelmann Molecular Magnetic Materials .................................. 335 Bing-Wu Wang and Song Gao Near-Infrared Materials ....................................... 347 Lining Sun and Liyi Shi Superconducting Materials ..................................... 371 Antonio J. Dos santos-Garcia, Miguel Á. Alario-Franco and Regina Sáez-Puche Metal-Organic Frameworks ...................................... 385 John Hamilton Walrod II and David A. Atwood Upconversion Nanoparticles for Bioimaging Applications ........ 389 Jiefu Jin and Wing-Tak Wong Oxide and Sulfide Nanomaterials ............................... 405 Takuya Tsuzuki Rare Earth Metal Cluster Complexes ............................ 415 Gerd Meyer Organic Synthesis ............................................. 437 Yuichiro Mori and Shũ Kobayashi Homogeneous Catalysis ......................................... 459 Yingming Yao and Кuп Nie Heterogeneous Catalysis ....................................... 475 John Hamilton Walrod II and David A. Atwood Supramolecular Chemistry: from Sensors and Imaging Agents to Functional Mononuclear and Polynuclear Self-Assembly Lanthanide Complexes .......................................... 481 Jonathan A. Kitchen and Thorfinnur Gunnlaugsson Endohedral Fullerenes ......................................... 495 Daniel L. Burriss and David A. Atwood Lanthanide Shift Reagents ..................................... 501 Carlos F.G.C. Geraides Lanthanides: Magnetic Resonance Imaging ....................... 521 Sophie Laurent, Luce Vander Eist, Sebastien Boutry and Robert N. Muller Luminescent Bioprobes ......................................... 535 Anne-Sophie Chauvin Sensors for Lanthanides and Actinides ......................... 561 Gabriela I. Vargas-Zúñiga and Jonathan L. Sessler Index ......................................................... 575